unit 2 Flashcards

1
Q

what is a chemical reaction?

A

a chemical reaction is the conversion of one or more substances into another substance.

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2
Q

what is stoichiometry?

A

the process of determining the amounts of substances in a chemical reaction.

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3
Q

limiting reactants?

A

whichever elements limits the reaction.

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4
Q

excess reaction?

A

the reactant which is left over after the reaction.

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5
Q

theoretical yield?

A

the mass of product that you calculate. the maximum amount of material that you can “theoretically” make from the reactants provided.

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6
Q

actual yield?

A

the mass of product that is recovered under experimental conditions.

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7
Q

percentage yield formula?

A

% = actual / theoretical x 100

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8
Q

solubility?

A

the maximum amount of solute that will dissolve in a given quantity of solvent at a specific temperature.

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9
Q

precipitate?

A

insoluble solid that separates from the solution.

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10
Q

precipitation reaction?

A

a precipitation reaction refers to the formation of an insoluble salt when two solutions containing soluble salts are combined.

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11
Q

what are ionic equations?

A

the dissolved species as free ions. only soluble compounds are split into ions.

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12
Q

acid-base reactions?

A

acid and base combines to produce a salt.

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13
Q

redox reactions?

A

oxidation and reduction half reactions.

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14
Q

oxidation?

A

loss of electrons, also the reducing agent. donates electrons to the reactant being reduced.

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15
Q

reduction?

A

gain of electrons. the reactant being reduced is the oxidising agent. accepts electrons from the reactant being oxidised.

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16
Q

oxidation number rules?

A

lone elements have ON of 0, ON is equal to charge on the ion, ON of oxygen is usually -2, hydrogen is +1, group 1 metals are +1, group 2 metals are +2 and Fl is -1.

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17
Q

types of redox reactions?

A

combination - A+B–>C
decomposition - C –> A+B
combustion - A + O2 –> B

18
Q

titration?

A

a solution of known concentration is gradually added to a solution of unknown concentration until the reaction between the two solutions is complete.

19
Q

standard solution?

A

a solution of accurately known concentration.

20
Q

energy?

A

the capacity to do work.

21
Q

radiant energy?

A

energy which comes from the sun and earth’s primary energy source.

22
Q

thermal energy?

A

is the energy associated with the random motion of atoms and molecules.

23
Q

heat?

A

the transfer of thermal energy between two bodies that are at different temperatures.

24
Q

chemical energy?

A

the energy stored within the bonds of chemical substances.

25
Q

temperature?

A

a measure of thermal energy.

26
Q

nuclear energy?

A

is the energy stored within the collection of neutrons and protons in the atom.

27
Q

potential energy?

A

is the energy available by virtue of an object’s position.

28
Q

thermochemistry?

A

the study of heat change in chemical reactions.

29
Q

the system?

A

the system is the specific part of the universe that is of interest in the study.

30
Q

exothermic reactions?

A

heat is released and given off by the system to the surroundings.

31
Q

endothermic reaction?

A

heat is absorbed by the system from the surroundings.

32
Q

specific heat?

A

the specific heat of a substance is the amount of heat required to raise the temperature of one gram of the substance by one degree celsius.

33
Q

heat capacity?

A

the heat capacity of a substance is the amount of heat required to raise the temperature of a given quantity of the substance by one degree celsius.

34
Q

thermodynamics?

A

the scientific study of the interconversion of heat and other types of energy.

35
Q

first law of thermodynamics?

A

energy can be converted from one form to another but cannot be created nor destroyed.

36
Q

first law equation?

A
changeE = q + w
w = -P(delta)V
37
Q

sign conventions for work and heat?

A

work done by the system on the surroundings (-), word done on the system by the surroundings (+), heat absorbed by the system from the surroundings (+), heat absorbed by the surroundings from the system (-).

38
Q

enthalpy?

A

used to quantify the heat flow into or out of a system in a process that occurs at a constant pressure.

39
Q

standard enthalpy of formation?

A

the heat change that results when one mole of a compound is formed from its elements at a pressure of 1 atm.

40
Q

standard enthalpy of reaction?

A

is the enthalpy of reaction carried out at 1 atm.

41
Q

hess’s law?

A

when reactants are converted to products, the change in enthalpy is the same whether the reaction takes place in one step or in a series of steps. Enthalpy is a state function. it doesn’t matter how you get there, only where you start and end.

42
Q

the enthalpy of solution?

A

the enthalpy of solution is the heat generated or absorbed when a certain amount of solute dissolves in a certain amount of solvent.