Unit 1 : Topic 1 Flashcards

Formulae, Equations and Amount of Substance

1
Q

What is the unit used for the amount of substance?

A

The unit used is the mole (mol).

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2
Q

How is the number of particles in a sample calculated?

A

The number of particles can be calculated using the formula: Number of particles = Moles × Avogadro constant.

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3
Q

What is the empirical formula of Fe₂O₄?

A

For the chemical formula Fe₂O₄, the empirical formula is FeO₂.

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4
Q

What is the molecular formula if the empirical formula is C₄H₃O₂ and the relative molecular mass is 166?

A

The molecular formula is determined as C₈H₆O₄ by comparing the molecular and empirical masses.

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5
Q

What is relative formula mass?

A

Relative formula mass is the sum of the relative atomic masses of all atoms in a formula unit, often used for ionic structures.

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6
Q

What is 2 mg/cm³ equivalent to in ppm?

A

Convert 2 mg/cm³ to μg/cm³, resulting in 2000 ppm.

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7
Q

What is concentration?

A

Concentration is the amount of solute per cubic decimeter of solution.

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8
Q

What is an ion?

A

An ion is an atom or a group of atoms that carries an electric charge due to the loss or gain of electrons.

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9
Q

How is concentration in mol/dm³ calculated?

A

Concentration in mol/dm³ is Moles ÷ Volume (dm³).

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10
Q

What is an ionic equation?

A

An ionic equation shows only the reacting ions in a solution and excludes spectator ions.

For example, Ag(aq) + Cl⁻(aq) → AgCl(s).

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11
Q

How many moles of iron are in a sample with 4.816 × 10²⁴ atoms?

A

Divide the number of atoms by the Avogadro constant, resulting in 8 moles of iron.

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12
Q

What does a chemical equation tell us about the number of moles of reactants and products?

A

The stoichiometric ratio indicates the relationship between reactants and products.

For example, C₃H₈ + 5O₂ → 3CO₂ + 4H₂O, one mole of propane produces four moles of water.

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13
Q

What is the empirical formula?

A

The empirical formula is the simplest ratio of the number of atoms of each element in a compound.

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14
Q

What is 1 ppm equivalent to?

A

For mass/volume concentrations, 1 ppm = 1 g/m³ = 1 mg/L = 1 μg/cm³. For mass/mass concentrations, 1 ppm = 1 mg/kg = 1 μg/g.

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15
Q

What is molar mass?

A

Molar mass refers to the mass of one mole of a substance, expressed in grams per mole.

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16
Q

What is the Avogadro constant?

A

The Avogadro constant is the number of particles in one mole, equal to 6.02 × 10²³.

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17
Q

What is parts per million (ppm)?

A

Parts per million measures the ratio of one substance to another.

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18
Q

How is the volume of a gas at RTP calculated?

A

The volume is Moles × 24.

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19
Q

What is a mole?

A

A mole refers to the amount of a substance containing the same number of particles as there are atoms in 12 grams of carbon-12.

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20
Q

What are the general products of a reaction between an acid and a metal?

A

The reaction produces a salt and hydrogen gas: Acid+Metal→Salt+ Hydrogen

21
Q

What is the percentage yield of ammonia if 40.5 g is produced from 20.0 mol of hydrogen with excess nitrogen?

A

For this reaction N2+3H2→2NH3
- The theoretical yield of ammonia is 227 g.
- The percentage yield is (40.5÷227)×100=17.9%

22
Q

What is the molecular formula?

A

The molecular formula shows the exact number of atoms of each element present in a compound.

23
Q

Why might the actual yield be less than the theoretical yield?

A
  • The reaction may be incomplete.
  • Side reactions may occur.
  • Practical losses during transfer of materials may happen.
24
Q

What is the ideal gas law?

A

The ideal gas law is PV = nRT, where P is pressure (Pa), V is volume (m³), n is moles, R is the gas constant (8.31 J/K·mol), and T is temperature (K).

25
What are precipitation reactions?
Precipitation reactions involve the reaction of two soluble salts to form an insoluble salt (precipitate).
26
How is concentration in g/dm³ calculated?
Concentration in g/dm³ is Mass (g) ÷ Volume (dm³).
27
How do you calculate the number of moles of a gas at a given temperature and pressure using the ideal gas law?
Using the equation = PV=nRT - Convert pressure to pascals, temperature to kelvin, and volume to cubic meters. - For example, at 55.0∘C55.0∘C, 275kPa275 kPa, and 1.10dm31.10 dm3 , 𝑛=0.10 moles n=0.10 moles.
28
What do the state symbols (g), (aq), (s), and (l) mean?
(g) represents gas. (aq) represents aqueous. (s) represents solid. (l) represents liquid.
29
What is an element?
An element consists of only one kind of atom.
30
What is relative molecular mass?
Relative molecular mass is the sum of the relative atomic masses of atoms in a molecule.
31
How are the number of moles of a substance calculated?
The number of moles is calculated as Mass ÷ Relative Molecular Mass.
32
What is relative atomic mass?
Relative atomic mass is the weighted average mass of an atom compared to one-twelfth of the mass of a carbon-12 atom.
33
What is the volume of 72 dm³ of oxygen at RTP in moles?
The number of moles is 72 ÷ 24 = 3.
34
What is the reaction between hydrochloric acid and sodium?
The reaction is: 2𝐻𝐶𝑙+2𝑁𝑎→2𝑁𝑎𝐶𝑙+𝐻2O ​
35
What is RTP?
RTP stands for room temperature and pressure, defined as 20 °C and 1 atmosphere.
36
What is 0.75 g/kg equivalent to in ppm?
Convert grams to milligrams, yielding 750 ppm.
37
What is the reaction between sulfuric acid and magnesium oxide?
The reaction is: 𝐻2𝑆𝑂4+𝑀𝑔𝑂→𝑀𝑔𝑆𝑂4+𝐻2O
38
What are the general products of a reaction between an acid and a metal oxide?
The reaction produces a salt and water: Acid+Metal oxide→Salt+ Water
39
What are the general products of a reaction between an acid and a metal carbonate?
The reaction produces a salt, water, and carbon dioxide: Acid+Metal carbonate→Salt+Water+Carbon dioxide
40
What is the molar volume of any gas at RTP?
At RTP, one mole of any gas occupies 24 dm³.
41
What is a molecule?
A molecule is formed when two or more atoms are chemically bonded together.
42
What is a compound?
A compound consists of molecules that contain atoms of different elements.
43
How is atom economy calculated?
The formula for atom economy is: Atom economy = (Molar mass of desired  product / total mass of products) x 100
44
What is the relationship between atom economy and sustainability?
A higher atom economy indicates a more sustainable and efficient process.
45
What is the reaction between bromine and potassium iodide?
The reaction is: 𝐵𝑟2+2𝐾𝐼→𝐼2+2𝐾𝐵𝑟
46
What is atom economy?
Atom economy measures the efficiency of a reaction by determining the proportion of reactants converted into useful products.
47
What is an atom?
An atom is the smallest unit of a chemical element.
48
How is percentage yield calculated?
Percentage yield is calculated as: Percentage yield = (actual yield/theoretical yield) x 100
49
What are displacement reactions?
Displacement reactions occur when one element replaces another in a compound. The general equation is: 𝐴+𝐵𝐶→𝐵+𝐴𝐶