Unit 1 Terms Flashcards
electronegativity
the ability of an atom to pull electrons to itself in a chemical bond [0.7 (low) - 4.0 (high) ]
Covalent Bonds
a. pure covalent bonds
- equal sharing of electrons [0 - 0.4]
b. polar covalent bonds
- unequal sharing of electrons [0.4 - 2.0]
Ionic bonds
- metal & non metal
- transfer of electrons
- NaCl [e.n. 2.0]
Dispersion Forces (London Forces)
weakest
- dominant force in atoms and in non polar molecules
- larger molecule atom
- more electrons
Dipole-Dipole
strong
- the larger the dipole moment, the greater the dipole-dipole forces
- cannot be non polar
if dipole dipole than aslso LDF
Hydrogen Bonds
super dipole-dipole moment,
- H-F, H-N, H-O
if H Bonding than it also has dipole dipole and LDF
Ion Dipole
- ionic compound mixed with polar compound the smaller the cation the higher the charge
Nonpolar (checklist)
- central atom has no lone pairs
- all atoms around are the same
(just C & H / LDF)
LDF
Polar (checklist)
- different atoms around
LDF, Dipole - Dipole (if asked dominant then d-d)
Compound with H - F, O, N (IMF)
LDF , D-D, Hydrogen Bonding
Crystalline solids
- have a highly ordered arrangement of particles (ions, atoms, molecules) ex. diamond , graphite, salt
Simple Cubic
coordination # 6
(8 corner atom) x (1/8 atom) = 1 atom / unit cell
volume unit cell: a ^3 = (2r)^3 = 8r^3
volume atom: 4/3π r^2
volume of total atoms: 4/3 (π) = 4.19 r^3
% occupied = volume of the total / volume of the unit cell x 100
% occupied = 4.19 r^3 / 8r^3 x 100 =