Unit 1: Section 2 - Amount of Substance Flashcards

1
Q

What is the Avogadro’s constant equation? (This is really helpful because you always forget it)

A

Number of particles = Number of moles x Avogadro’s constant

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2
Q

What is the definition of Avogadro’s constant?

A

Number of particles/atoms/ions in one mole of a substance

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3
Q

What is the moles, mass equation?

A

Mass of substance = Number of moles x Mr

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4
Q

What is the moles, concentration equation?

A

Number of moles = Concentration x Volume

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5
Q

What is the Ideal Gas equation including the units?

A

pV=nRT
p - pressure in Pa
V - volume in m^3
n - number of moles
R - gas constant in JK^-1mol^-1
T - temperature in K

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6
Q

What are standard conditions?

A

25°C/298K
1 atm/ 100kPa

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7
Q

How do you write an ionic equation?

A
  1. Write the balanced symbol equation
  2. Identify the soluble compounds using the solubility rules or the aqueous state symbol
  3. Split up the soluble compounds into ions
  4. Cancel ions that appear on both sides of the equation
  5. Write out the resulting ionic equation
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8
Q

How to make a standard solution (Using sodium hydroxide)?

A
  1. Work out how many moles of NaOH you need using moles = concentration x volume
  2. Work out how many grams of NaOH you need using mass = moles x Mr
  3. Use weighing by difference to find the precise mass of the solid used and add to beaker making sure to rinse the washings
  4. Add distilled water to the beaker and stir
    until all NaOH has been dissolved
  5. Tip the solution into a volumetric flask using a funnel
  6. Rinse the beaker and stirring rod with distilled water and add that to the flask, making sure there’s no solute left over
  7. Use distilled water to fill the flask up to the line, making sure the bottom of the meniscus is lined up
  8. Stopper and invert the flask a few times to ensure it’s all been mixed
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9
Q

How to set up a titration

A
  1. Use a pipette to measure a set volume of the solution you want to know the concentration of, and put it in a flask
  2. Add a few drops of indicator
  3. Then fill a burette with a standard solution of the acid that you know the exact concentration of
  4. Use a funnel to carefully pour the acid into the burette, always doing this below eye level
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10
Q

How to carry out a titration

A
  1. Do a rough titration to get an idea where the end point actually is
  2. Take an initial reading to see exactly how much acid is in the burette, then run the acid within 2cm^3 of the rough titre, then add it dropwise, swirling the flask until the colour just changes
  3. Work out the amount of acid required to neutralise the alkali
  4. Repeat until you have three concordant results
  5. Calculate a mean value
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11
Q

What are the titration indicators?

A

Methyl orange - red in acid and yellow in alkali
Phenolphthalein - colourless in acid and pink in alkali
Use a white tile to be bale to see the colour change easier

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12
Q

What is the empirical formula?

A

The simplest whole number ratio of atoms of each element in a compound

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13
Q

What is the molecular formula?

A

Gives the actual numbers of atoms of each element in a compound

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14
Q

What is theoretical yield?

A

The mass of product that should be formed in a chemical reaction, it assumes no chemicals are ‘lost’ in the process.
You can use the masses of reactants and a balanced equation to calculate it

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15
Q

How to calculate percentage yield

A

Percentage Yield = Actual Yield / Theoretical Yield x 100

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16
Q

What is percentage yield?

A

Tells you how wasteful a process is, based on how much product is lost during the process

17
Q

What is atom economy?

A

The measure of the proportion of reactant atoms that become part of the desired product rather than the by-products in the balanced chemical equation

18
Q

How to calculate atom economy

A

Percentage Atom Economy = Molecular mass of desired products / Sum of molecular masses of all reactants x 100

19
Q

Why do companies in industry want a high atom economy?

A
  1. Better for the environment because they produce less waste
  2. They make more efficient use of raw materials, so they’re more sustainable
  3. They are less expensive because they need to spend less time separating the desired product from the waste products, and less on treating waste