Unit 1: Section 12- Acids and Bases + RP 9 Flashcards
Define a Bronsted-Lowry acid
a substance that can donate a proton
Define a Bronsted-Lowry base
a substance that can accept a proton
What is the equation for calculating pH?
pH = log[H+]
What does [H+] represent?
the concentration of the hydrogen ions in the solution
Define strong acid
they fully dissociate
What is a monoprotic acid?
an acid that donates one H+ ion or proton per every molecule when it dissociates with water
How many d.p. values is pH given to?
2d.p.
How do you rearrange the pH equation to find [H+]?
[H+] = 1 x 10 ^-pH
What is the equilibrium equation that occurs in all aqueous solutions and pure water?
H2O (l) ⇌ H+ (aq) + OH- (aq)
Why is Kw used and not Kc?
because [H2O (l)] is much bigger than the concentrations of the ions, we assume its value is constant and make a new value, Kw
What is the Kw expression?
Kw = [H+ (aq)] [OH- (aq)]
What type of compound are weak acids usually?
organic
What type of compound are strong acids usually?
inorganic
What is a diprotic acid?
donates two hydrogen ions (H2SO4), the [H+] is 2x that of the acid
How can the Kw equation be rewritten for pure and neutral solutions?
Kw = ([H+])²
because [OH-] = [H+]
What is the Kw value of an aqueous solution at room temp (25°C)?
1.0 x 10^-14 mol^2 dm^-6
define strong base
they completely dissociate into their ions in solution
How to calculate pH of strong base
1) use pH equation
2) use Kw equation
3) pH of a base = -log√Kw
What is Kw?
the ionic product of water, 1.0 x 10^-14 mol^2 dm^-6
Define weak acid
only partially dissociate into their ions in solution
What is Ka?
the acid dissociation constant
What does the size of the Ka value mean?
larger Ka= compounds that dissociate more completely into solution, stronger acids
smaller Ka= weaker acids
What is the Ka equation?
Ka = [H+]² / [HA]initial
What are the two key assumptions when using Ka to calculate the pH of weak acids?
- that [H+] = [A-]
- that conc of HA at equilibrium is the same as initial conc of the acid because of small dissociation
What is the equation for converting pKa into Ka?
Ka = 10 ^-pKa
What is pKa?
the negative logarithm of Ka