Unit 1: Section 12- Acids and Bases + RP 9 Flashcards

1
Q

Define a Bronsted-Lowry acid

A

a substance that can donate a proton

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Define a Bronsted-Lowry base

A

a substance that can accept a proton

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What is the equation for calculating pH?

A

pH = log[H+]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What does [H+] represent?

A

the concentration of the hydrogen ions in the solution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Define strong acid

A

they fully dissociate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What is a monoprotic acid?

A

an acid that donates one H+ ion or proton per every molecule when it dissociates with water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

How many d.p. values is pH given to?

A

2d.p.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

How do you rearrange the pH equation to find [H+]?

A

[H+] = 1 x 10 ^-pH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What is the equilibrium equation that occurs in all aqueous solutions and pure water?

A

H2O (l) ⇌ H+ (aq) + OH- (aq)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Why is Kw used and not Kc?

A

because [H2O (l)] is much bigger than the concentrations of the ions, we assume its value is constant and make a new value, Kw

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What is the Kw expression?

A

Kw = [H+ (aq)] [OH- (aq)]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What type of compound are weak acids usually?

A

organic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What type of compound are strong acids usually?

A

inorganic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What is a diprotic acid?

A

donates two hydrogen ions (H2SO4), the [H+] is 2x that of the acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

How can the Kw equation be rewritten for pure and neutral solutions?

A

Kw = ([H+])²
because [OH-] = [H+]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is the Kw value of an aqueous solution at room temp (25°C)?

A

1.0 x 10^-14 mol^2 dm^-6

17
Q

define strong base

A

they completely dissociate into their ions in solution

18
Q

How to calculate pH of strong base

A

1) use pH equation
2) use Kw equation
3) pH of a base = -log√Kw

19
Q

What is Kw?

A

the ionic product of water, 1.0 x 10^-14 mol^2 dm^-6

20
Q

Define weak acid

A

only partially dissociate into their ions in solution

21
Q

What is Ka?

A

the acid dissociation constant

22
Q

What does the size of the Ka value mean?

A

larger Ka= compounds that dissociate more completely into solution, stronger acids

smaller Ka= weaker acids

23
Q

What is the Ka equation?

A

Ka = [H+]² / [HA]initial

24
Q

What are the two key assumptions when using Ka to calculate the pH of weak acids?

A
  1. that [H+] = [A-]
  2. that conc of HA at equilibrium is the same as initial conc of the acid because of small dissociation
25
Q

What is the equation for converting pKa into Ka?

A

Ka = 10 ^-pKa

26
Q

What is pKa?

A

the negative logarithm of Ka

27
Q
A