Unit 1 Kinetic Theory and Heat Transfer Flashcards
What is the definition of ‘kinetic theory’?
Kinetic theory describes matter as very large numbers of atoms and molecules in constant motion.
Describe the properties of solids
-particles are packed very closely together in a regular arrangement.
-they vibrate about a fixed positions and have strong forces of attraction between them (bonds).
-as a result they have a fixed shape and volume and a high density.
Describe the properties of liquids
-particles are closer together, but not as close as they are in solids. The particles are mainly touching but some gaps have appeared in the structure.
-they have enough energy to move around and are not held in fixed positions; bonds are weaker than in solids.
-liquids have a fixed volume but take on the shape of the bottom of the container; they have a medium density.
Describes the properties of gases
-particles are very far apart and can move around rapidly and randomly in any direction; very weak bonds.
-no fixed shape or volume- they completely fill their container.
-low density.
What happens to the density of a solid substance when it changes to a liquid?
If a solid changes to a liquid, its mass would stay the same but (usually) its volume would increase since the distance between the particles in a liquid is greater than in a solid. This means that the density would decreases, as you are dividing the mass by a larger number.
What happens to the density of a liquid substance when it changes to a gas?
If a liquid changes to a gas, its mass would stay the same but (usually) its volume would increase since the distance between the particles in a gas is greater than in a liquid. This means that the density would decreases, as you are dividing the mass by a larger number.
What is the summary for density?
-In solids, since the particles are packed very close together they have a high density.
-In liquids, the molecules are close together, but not as close as they are in solids; they have a medium density.
-In gases, the particles are very far apart with large distances between them; they have a low density.
What are the two factors which allow heat transfer most quickly?
- The temperature difference is greatest
- The surface area is greatest
What are the three main methods of heat transfer?
Conduction, convection and radiation
What is conduction?
Conduction is the transfer of heat energy through a substance by particle collisions (it occurs mainly in solids).
How do solids conduct?
As the solid gets heated its particles absorb heat energy and convert this to kinetic energy and so they start to vibrate more vigorously. In other words, they vibrate faster and with greater amplitude, and so collide with neighbouring particles with more force and more often, which in turn causes these particles to vibrate more vigorously too, and in this way the energy is passed along/ through the solid in the form of kinetic energy.
Why are metals better conductors than non-metals
Metals contain free electrons; which can move freely throughout the solid. When a metal is heated, the free electrons move from hot parts of the metal to colder parts, taking heat energy with them (electron diffusion). As they move through the metal the free electrons collide with atoms and in these collisions, the electrons transfer some of their energy to the atoms and cause them to vibrate more vigorously than before.
Metals conduct by both particle vibration and free electron movement
Why are liquids and gases poor conductors?
Most liquids have no free electrons, so rely on passing vibrations from atom to atom, but the particles are further apart than in solids, meaning there are less particle collisions.
Particles in gases are too spread out to affect each other through particle collisions.
What is convection?
Convection is the transfer of heat in a fluid (liquid or gas) due to the particles within the fluid moving around through it, as a result the density changes.
When a fluid is heated its particles gain kinetic energy and the fastest-moving particles in a hot region of the substance will move to a cooler region
How are convection currents set up?
When you heat a liquid or gas its particles gain energy and begin to move faster and further apart. This means that the particles are spread out over a greater volume - the fluid expands, making the fluid less dense. The warmer, less dense fluid rises above its colder, denser surroundings. As the warm fluid rises, cooler fluid moves in to take its place, setting up a convection current.
CONVECTION CANNOT OCCUR IN SOLIDS since the particles within the solids are not free to move from place to place; they can only vibrate