Unit 1: Atomic Structure, Periodicity, Trends on the Periodic Table Flashcards

1
Q

Allotropes

A

2 versions of the same element

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2
Q

Protons

A

Charge: +1
Mass: 1
Location: Nucleus

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3
Q

Neutrons

A

Charge: 0
Mass: 1
Location: Nucleus

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4
Q

Electrons

A

Charge: -1
Mass: 0
Location: Valence shells

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5
Q

Atomic mass =

A

fractional abundance x mass number

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6
Q

Mass spectrometer

A

seperates atoms by mass

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7
Q

n is the?

A

principle energy level

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8
Q

Number of electrons in each level

A

2n^2

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9
Q

sublevel: S

A

holds 2 electrons, 1 orbital, sphere

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10
Q

sublevel: P

A

holds 6 electrons, 3 orbitals, teardrops

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11
Q

sublevel: D

A

holds 10 electrons, 5 orbitals

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12
Q

sublevel: F

A

holds 14 electrons, 7 orbitals

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13
Q

electrons in orbitals…..

A

have different spins ↑↓

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14
Q

ground state

A

as close to the nucleus as an electron can get

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15
Q

Aufbau principle

A

another way to put the electron configuration in order

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16
Q

electron configuration shortcut

A

go to the nearest noble gas
e.g. [Ar] 4s2 3d10 4p3

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17
Q

what type of sublevels are more stable?

A

half-filled sublevels and full sublevels

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18
Q

isoelectronic

A

‘same configuration’

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19
Q

c=λv

A

c: speed of light
λ: wavelength
v: frequency

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20
Q

E=hv

A

Equation for the incoming energy of electromagnetic radiation
E: energy
h: planck’s constant
v: frequency

21
Q

Longer wavelengths have….

A

lower frequency

22
Q

Shorter wavlengths have….

A

higher frequency

23
Q

Periodicity

A

repeating patterns of physical and chemical properties

24
Q

Metals tend to….

A

lose electrons

25
Q

Non-metals tend to….

A

gain electrons

26
Q

Atomic radius trend

A

increases down and to the left, focuses on electrons

27
Q

Shielding

A

increases down and to the right, focuses on protons

28
Q

1st ionization energy

A

energy to remove an electron, increases up and to the right

29
Q

Electronegativity

A

attraction an atom has for the electrons in a bond, closest to Fluorine in the most electronegative, increases up and to the right, covalent < 1.7 < ionic

30
Q

Electron affinity

A

energy released when one electron is added to a neutral atom in the gas state (exothermic), adding second electron is endothermic, increases up and to the right

31
Q

Melting point

A

transition metals have a high melting point, metaks have a low melting point, carbon’s family has a high melting point, diamond has the highest melting point.
The more metals in the valence, the harder the metals, the higher the metling point.

32
Q

Basic oxides

A

Metals: tend to lose electrons, tend to be ionic oxides

33
Q

Acidic oxides

A

Non-metals: tend to gain electrons, tend to be covalent oxides

34
Q

Amphoteric

A

it acts as a base in some situations and an acid in others - e.g. Al2O3

35
Q

Transition metals

A

incomplete ‘d’ sublevel, Zn is an exception

36
Q

Variable oxidation states

A

just a broader term for the charge

37
Q

Ligands

A

complex ions, ligands are lewis bases, metal ions are lewis bases, lewis acid recieves the lone pair, lewis base provides the lone pair, must use square brackets for complex ions

38
Q

Coordinate covalent bond

A

one atom provides both electrons for covalent bonds

39
Q

Dimagentism

A

only paired electrons, commonly ‘non-magnetic’, weak repulsion in a magnetic field

40
Q

Paramagnetism

A

half-filled orbitals, the more half-filled orbitals the more magnetic, strong repulsion in a magnetic field

41
Q

Ferromagnetism

A

lots of half-filled orbitals, everday magnetism, Fe, Co, Ni

42
Q

Catalyst

A

something that causes a reaction to go faster, increases reaction rate, the catalyst is unchanged during the reaction

43
Q

Heterogeneous

A

transition metals

44
Q

Homogeneous

A

enzymes, Iron (II), Cobalt (III)

45
Q

Colorwheel

A

transition metals often have bright colors, complimentary colors are opposite, Sc3+ is colorless (there are no electrons in a d sublevel)

46
Q

Photons of visible light can….

A

promote (raise) an electron to a slightly higher energy level

47
Q

4 factors

A

identity of a ligand, identity of the metal ion, geometry, oxidation state on the metal ion

48
Q

LEO says GER

A

LEO: loss of electrons, oxidation - reducing agent, causes reduction
GER: gain of electrons, reduction - oxidizing agent, causes oxidation