Unit 1 Flashcards
Alkane/ ene/ yne polarity
Non polar
Alkane/ ene/ yne main intermolecular force
London dispersion
Alkane/ ene/ yne Mp/Bp
Low but get higher as the chain gets longer
Organic Halides polarity
More polar than hydrocarbons which means higher mp/ bp and more soluble. The more halogens there are, the more polar it gets
Alcohols polarity
Polar, they form hydrogen bonds so higher mp/ bp
Short chain alcohols are good polar solvents
Long chain alcohols are good polar and non polar solvents
Ethers polarity
Can not form hydrogen bonds but the oxygen makes it more polar than alkanes
Good as a polar and non polar solvent because it is very chemically stable
Aldehydes and ketones polarity
Both polar and non polar, good solvents. Less soluble in water that alcohol because there is no hydrogen bonding
Ethers mp/bp
Mp/ bp is higher than alkanes but lower that alcohols and water
Aldehydes and ketones mp/ bp
Lower than alcohols
Carboxylic acids polarity
Polar and form hydrogen bonds
Similar solubilities to alcohols
Behave like other acids
Carboxylic acids mp/bp
higher mp/bp than alcohols
Which side of esters goes first
Carboxylic acid
Ester polarity
Less polar than the parent acid and alcohol which leads to lower mp/ bp
Ester at room temp
Gasses. Lower molecular mass
Amines mp/bp
Higher than alkanes
Amines solubility
Smaller molecules are more soluble
Amines smell
Fishy
Amines Types of bonds
Hydrogen bonds
Amines Bond polarity
Polar
Amides properties
Weak bases, H+ receivers
Amides solubility
Not soluble in water
Amides Mp/ bp
If alkyl group is on the end they have lower mp/bp that if NH2 group is on the end
Addition polymers
linkage by unsaturated carbon bonds
Polyesters
Made from a dicarboxylic acid and a diol
Polyamides
Made from an anime group and a carboxylic acid
Alkanes substitution
Br2 turns into HBr
Halogenation
Br2 breaks a double bond
Hydrogenation
H2 breaks a bond (needs to be balanced)
Hydrohalogenation
HBR breaks double bonds
Hydration
H2O is used to form am alcohol
Elimination (organic halides)
Strong acid or base is used to remove a halogen
Dehydration (alcohols)
Alcohol turns into water and an alkene
Condensation (ethers)
How an ether is formed
Synthesis (A+K)
Aldehydes and keynote are formed
Esterification
An ester is formed
Hydrolysis/ saponificantion
A carboxylic acid and alcohol are formed from an ester
Synthesis (amides)
Adding NH3 to a carboxylic acid
Hydrolysis (amides)
Breaks them apart