Unit 1 Flashcards

1
Q

What is science?

A

The study of the physical and natural world through observations and experiments.

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2
Q

What is chemistry?

A

The study of matter and its transformations. Matter is composed of atoms.

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3
Q

State the main points of Dalton’s atomic theory.

A
  1. Matter is composed of atoms.
  2. Elements consist of one type of atom.
  3. Atoms of one element differ from others.
  4. Compounds consist of atoms in whole-number ratios.
  5. Atoms are not created or destroyed in a chemical change
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4
Q

What law does Dalton’s atomic theory support?

A

Law of conservation of matter, constant composition, and multiple proportions.

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5
Q

Who discovered the electron?

A

A: J.J. Thomson through the cathode ray tube experiment.

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6
Q

Q: What are the three conclusions of Thomson’s experiment?

A

A:
1. Electrons are negatively charged particles.
2. They are smaller than atoms.
3. Electrons are the same for all elements.

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7
Q

Q: What was Millikan’s contribution to atomic theory?

A

A: He measured the charge of the electron using the oil drop experiment.

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8
Q

Q: What did Rutherford’s alpha scattering experiment demonstrate?

A

A: It led to the discovery of the nucleus, proving the atom has a dense, positively charged center.

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9
Q

Q: What are the charges and masses of protons, neutrons, and electrons?

A

A:
- Proton: +1, 1.67 × 10⁻²⁷ kg
- Neutron: 0, 1.67 × 10⁻²⁷ kg
- Electron: -1, 9.11 × 10⁻³¹ kg

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10
Q

Q: What are isotopes?

A

A: Atoms of the same element with the same number of protons but different numbers of neutrons.

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11
Q

Q: Define ions.

A

A: Atoms or groups of atoms with a net charge due to loss or gain of electrons.

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12
Q

Q: What is a cation?

A

A: A positively charged ion (loses electrons).

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13
Q

Q: What is an anion?

A

A: A negatively charged ion (gains electrons).

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14
Q

Q: What is a chemical symbol?

A

A: A notation of one or two letters representing an element (e.g., H for hydrogen).

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15
Q

Q: How do you calculate mass number?

A

A: Mass number = protons + neutrons.

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16
Q

Q: What are ionic compounds?

A

A: Compounds formed by the combination of metal and non-metal ions.

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17
Q

Q: Name the compound: FeCl₃.

A

A: Iron (III) chloride.

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18
Q

Q: What are covalent compounds?

A

A: Compounds formed between non-metals through shared electrons.

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19
Q

Q: Name the compound: N₂O.

A

A: Dinitrogen monoxide.

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20
Q

Q: Define binary acids.

A

A: Acids containing hydrogen and one non-metal, named with the “hydro-ic” suffix.

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21
Q

Q: What is Planck’s equation?

A

A: E = hν, where h = Planck’s constant and ν = frequency.

22
Q

Q: State Planck’s constant.

A

A: 6.626 × 10⁻³⁴ Js.

23
Q

Q: What is the photoelectric effect?

A

A: Emission of electrons from a metal when light of sufficient frequency shines on it.

24
Q

Q: What is the threshold frequency?

A

A: The minimum frequency needed to eject electrons in the photoelectric effect.

25
**Q:** Who proposed the Bohr model of the atom?
**A:** Niels Bohr in 1913.
26
**Q:** State Bohr's postulates.
**A:** Electrons orbit in stationary states and emit/absorb energy when transitioning between levels.
27
**Q:** What is the Rydberg constant?
**A:** 2.179 × 10⁻¹⁸ J.
28
**Q:** Define quantum numbers.
**A:** Numbers describing an electron's position: n, l, ml, ms.
29
**Q:** What does the principal quantum number (n) define?
**A:** The size and energy of an orbital.
30
**Q:** What does the angular momentum quantum number (l) define?
**A:** The shape of the orbital (s, p, d, f).
31
**Q:** What are degenerate orbitals?
**A:** Orbitals with the same energy.
32
**Q:** What does Heisenberg's uncertainty principle state?
**A:** It is impossible to know both the position and momentum of a particle simultaneously.
33
**Q:** What is an orbital?
**A:** A region in space where the probability of finding an electron is highest.
34
**Q:** State Pauli’s exclusion principle.
**A:** No two electrons in an atom can have the same set of four quantum numbers.
35
**Q:** What is Hund's rule?
**A:** Electrons occupy degenerate orbitals singly before pairing.
36
**Q:** What is the Aufbau principle?
**A:** Electrons fill orbitals starting with the lowest energy level.
37
**Q:** What is electronic configuration?
**A:** Distribution of electrons in orbitals of an atom.
38
**Q:** Write the electronic configuration for Fe²⁺.
**A:** [Ar] 3d⁶.
39
**Q:** How does atomic size change across a period?
**A:** It decreases.
40
**Q:** How does atomic size change down a group?
**A:** It increases.
41
**Q:** Define ionization energy.
**A:** The energy required to remove an electron from an atom in the gaseous state.
42
**Q:** How does ionization energy change across a period?
**A:** It increases.
43
**Q:** What is electron affinity?
**A:** The energy change when an atom gains an electron.
44
**Q:** Define shielding effect.
**A:** Inner electrons shield outer electrons from nuclear attraction.
45
**Q:** What are acidic oxides?
**A:** Oxides of non-metals that react with water to form acids.
46
**Q:** What are basic oxides?
**A:** Oxides of metals that react with water to form bases.
47
**Q:** What are amphoteric oxides?
**A:** Oxides that react with both acids and bases (e.g., Al₂O₃).
48
**Q:** What is a reducing agent?
**A:** A substance that donates electrons in a reaction.
49
**Q:** What is the flame color of lithium?
**A:** Red.
50
**Q:** Why don’t Mg and Be produce flame colors?
**A:** Their electrons require too much energy to excite.