TUT 04 : SCMs and admixtures Flashcards

1
Q

name four common supplementary cementing materials and describe where they come from

A
  • blast funace slag - waste from smelting iron
  • fly ash - residue from burning coal
  • silica fume - residue from silicon production
  • calcined clay - modified natural mineral
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2
Q

name all four types of chemical admixtures and explain why one would use them

A
  • air entraining. - to add entrained air to resist freeze-thaw damage
  • water reducing - to reduce w/c and or increase workability
  • set accelerating - to increase early strength developpement
  • set retarding - to increase workability time
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3
Q

explain how air entrainment helps protect against but does not prevent freeze-thaw damage

A
  • impermeable entrained air bubbles are formed in cement paste
  • water fills permeable entrapped air bubbles and freezes and begins to expand
  • cracks form to find a place for water t expand but when there is no space to accommodate the expansion, the cracks are large
  • cracks follow path of least resistance and reach entrained air voids (crack easily), cracks enter entrained air voids, provide space for water to expand in
  • damage is not prevented becasue cracks still occur but mititgates gamage by reducing severity of cracking
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4
Q

what does SCM mean

A

supplementary cementitious materials
- also know as admixtures

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5
Q

what is SCM’s (use)

A

finely grained particles added to portland cement concrete and mortar mixes to obtain specific engineering properties

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6
Q

what is a chemical admixture

A

adding small amounts of materials (dissolved in mixing water) to concrete
- changes physical properties of fresh and hard concrete

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7
Q

what are the types of SCM’s

A
  • cementitious and pozzolanic
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8
Q

what are the advantages of scm’s

A
  • economic
  • sustainable
  • increases durability
  • alternative to cement and other materials
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9
Q

example of cementitious scm and what is needed for it to react

A
  • blast furnace slag - comes from smelting of iron
  • reacts with water alone
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10
Q

example of pozzolanic scm and what is needed for it to react

A
  • fly ash - residue from coal production
  • silica fume - residue from silicon production
  • calcified clay - from modified clay

needed to react: calcium hydroxide and water

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11
Q

what are the microscopic properties of CH

A
  • thin, hexagonal plates
  • higher surface to volume ratio
  • highly reactive
  • leaches during efflorescence
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12
Q

what are the microscopic properties of CSH

A
  • dense, amorphous, crystalline structure
  • interstitial pores are too dense for water flow
  • responsible for impermeability
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13
Q

what are the 4 common types of chemical admixtures

A
  • water reducing
  • air entraining
  • set retarding
  • set acceleration
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14
Q

how does air entraining work?

A
  • surfactants act at air-water interface
  • create stable microscopic bubbles of foam from mixing
  • have one hydrophobic end and one hydropholic end
  • results in stable bubble that persits through hydration by volume of concrete
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15
Q

whats the difference between entrained air and entrapped air

A
  • entrained air:
    intentional (added by using admixtures), consistent in size, uniformely dispersed, waterproof even after concrerte hardens
  • entrapped air:
    accidental added by mixing, placing and consilidation mistakes
  • reduced by proper compaction
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16
Q

what are advantages of entrained air

A
  • increases resistance to freeze-thaw
  • increases resistance to sulphate attack
  • decreases material segregation
  • increases workability
17
Q

what are the disadvantages of entrained air

A
  • lowers strength
    (but concrete wouldnt be able to survive in environment without it)
18
Q

what are the important caracteristics that need to be taken into account with entrained air

A
  • amount: 4-7% by volume
  • must be dispersed but closed
  • cant be interconnected
19
Q

how does water reducing work

A
  • acts as a dispersants
  • makes the concrete more workable
  • prevents flocculation
  • allows absorption at surface of cement grains which changing surface properties
  • creates ionic repulsion
20
Q

what does water reducing do

A

decreases the w/c ratio for the same workability

21
Q

what does a plasticizer do

A

increases workability for the same W/C ratio

22
Q

what are the effects of water reducing

A
  • improves workability
  • increases strength for same cement content
  • increases ultimate strength
  • decreases air content
23
Q

how do set accelerating work

A
  • by providing additional calcium species in the early hydration reactions
  • increases rate of early strength developement
  • most commonly used is calcium chloride
24
Q

effects of set accelerators

A
  • speeds up setting time
  • increases drying shrinkage
25
Q

how deos set retarding work

A
  • slows down rate of early hydration reaction
  • decreases rate of early strength developement
  • creates parafilm
26
Q

what are the effects of set reducers

A
  • delays set time
  • increases workability time
  • will not affect ultimate strength