Trends In PTE Flashcards
Know what atomic Radius is, ionic Radius, electronegativity, ionization energy, electron affinity
What is Atomic Radius
from top to bottom, atomic radius ____
L–>R, atomic radius _____
As u move from top to bottom, atomic radius INCREASES because another energy level is added
L–>R, atomic radius DECREASES because of the inxrease in positive charge of the nucleus. This creates a stronger force of attraction between the electrons and nucleus, resulting in a smaller atomic Radius.
What group has the smallest atoms in their respective period?
The noble gases
What is Ionic radius
Describe it
Size of an atom when the atom gains (anion) an electron or loses an electron (cation)
+ve ions are always SMALLER than their corresponding neutral atom because a valence electron was removed. Force is shared among fewer electrons creating a stronger force of attraction between the nucleus and electrons. Loses valence electrons–>valence shell removed
-ve ions are BIGGER than their neutral atom. This is because there’s a stronger force of repulsion between electrons, causing them to spread apart. The nucleus can’t hold them so close together anymore, resulting in larger atomic Radius.
What is ionization energy
Energy required to remove an electron from an atom. Increases moving L-->R ---------> | | decreases from top-->bottom ☆
Why does ionization energy ____ from L–>R
ionization energy INCREASES from L–>R because:
- there’s a stronger attraction to the positively charged nucleus. This requires more energy to break this bond, hence why there’s an increase in ionization energy.
- The atomic Radius is smaller so electrons are closer to the nucleus, making it more difficult to break the bond of attraction between them
Why does ionization energy ____ from top to bottom
Ionization energy DECREASES from top to bottom because:
- There are more energy levels added on so there’s an increase in distance between the valence electrons and the positively charged nucleus. Less energy is required to remove the valence electron from the atom
What is electronegativity
The ability of an atom to attract shared pair of electrons in a chemical bond
Electronegativity:
___ down a group and ____ across a period from L->R
Yg
Electronegativity:
___ down a group and ____ across a period from L->R
Electronegativity DECREASES from top to bottom because as the size of the atom decreases, the valence electrons are closer to the nucleus. It doesn’t take much electronegativity to attract electrons because they’re closer to the nucleus already.
Electronegativity INCREASES from L–>R because there’s a strong positive charge in the nucleus that pulls electrons closer to the nucleus. It requires more energy to pull the electrons away.
The atomic Radius decreases so valence electrons are closer to the nucleus
Electronegativity:
___ down a group and ____ across a period from L->R
Electronegativity decreases from top to bottom
Atoms with HIGH electronegativities tend to ____ the nucleus
Pull electrons closer/towards
Atoms with LOW electronegativities tend to ___ the nucleus
Pull electrons FURTHER AWAY from the nucleus
Electronegativity of <0.4
Non polar covalent bond
Electronegativity between 0.5
Polar covalent bond
EN>1.8
Ionic bond