Transition Metals Colour Changes Flashcards
[Cu(H2O6)]^2+
from CuSO4.H2O (s)
Pale Blue
Fe3+ (aq) + 3OH- (aq) –> Fe(OH)3 (s)
yellow —> orange brown precipitate
Fe2+ (aq) + 2OH- —> Fe(OH)2 (s)
pale green –> dark green precipitate
Cu2+ (aq) 2OH- —> Cu(OH)2(s)
pale blue –> pale blue precipitate
Mn2+ (aq) + 2OH- —> Mn(OH)2(s)
pale pink —> pale brown precipitate
Cr3+ (aq) + 3OH- (aq) —> Cr(OH)3(s)
violet / pale purple —> dark green precipitate
Cr(OH)3(s) + 3OH - (aq) —> [Cr(OH)6]3- (aq)
dark green precipitate —> dark green solution
[Cu(NH3)4(H2O)2]2+
excess NH3 to Cu2+ (aq)
dark blue
CuCl4 2-
excess HCL to Cu2+ (aq)
yellow
Cu+
reduction of Cu2+ with I-
White precipitate (Cu) and brown I2
Cu2+ / Cu
Disproportionation of Cu+
brown solid (Cu) and blue solution (CuSO4)
CoCl4 2-
from CoCl2.6H2O(s) + water and excess HCl
blue
[Cr(H2O)6]3+
from KCr(SO4)2.12H2O(s)
pale purple (heat = green)
Due to impurities the Cr(III) can appear green in solution.
Cr(OH)3
NH3 dropwise to Cr3+ (aq)
dark green precipitate