Transition Metals Flashcards

1
Q

Chemical properties of TM?

A
  • variable oxidation states in compounds
  • form colored compounds and ions
  • often show catalytic activity (act as catalyst)
  • forms stable complexes
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2
Q

Acidity of oxidation states (TM)

A

Oxides with low ON tend to be basic (ionic) MnO
Oxides with high ON tend to be acidic (covalent) Mn2O7

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3
Q

Colours of Cu compounds?
1. Cu2+

A
  1. Cu2+: blue
  2. [Cu(NH3)4(H2O)2]2+ : dark blue
  3. [CuCl4]2- : yellow
  4. Cu2O: brick red solid
  5. Cu(OH)2: blue (solid)
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4
Q

Catalyst pathway?

A
  1. Adsorption of rxts by catalyst surface
  2. weak imf form btwn rxt and catalyst
  3. all rxts brough closer & rxn at surface occurs
  4. deadsorption of products to regen catalyst
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