Transition Metals Flashcards
1
Q
Chemical properties of TM?
A
- variable oxidation states in compounds
- form colored compounds and ions
- often show catalytic activity (act as catalyst)
- forms stable complexes
2
Q
Acidity of oxidation states (TM)
A
Oxides with low ON tend to be basic (ionic) MnO
Oxides with high ON tend to be acidic (covalent) Mn2O7
3
Q
Colours of Cu compounds?
1. Cu2+
A
- Cu2+: blue
- [Cu(NH3)4(H2O)2]2+ : dark blue
- [CuCl4]2- : yellow
- Cu2O: brick red solid
- Cu(OH)2: blue (solid)
4
Q
Catalyst pathway?
A
- Adsorption of rxts by catalyst surface
- weak imf form btwn rxt and catalyst
- all rxts brough closer & rxn at surface occurs
- deadsorption of products to regen catalyst