Transition Metals Flashcards

1
Q

What is platinum used as a catalyst in?

A

hydrogen fuel cells

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2
Q

what does nickel catalyse the production of amines from?

A

nitriles

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3
Q

light rays in order

A

radio waves
microwaves
infrared
visible light
ultraviolet
x rays
gamma rays

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4
Q

what do the frequencies in the visible light range correspond to?

A

different colours of light

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5
Q

what happens when all the frequencies of the different coloured lights are combined?

A

the light appears white

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6
Q

what happens when an object absorbs yellow light?

A

it appears blue

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7
Q

why are yellow and blue considered complementary colours?

A

blue and yellow completed each other
when put together they form white light

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8
Q

which colour is complimentary to red?

A

cyan

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9
Q

what is magentas complementary colour?

A

green

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10
Q

when do we see objects as coloured?

A

when they absorb some frequencies of visible light
but transmit or reflect other frequencies of visible light

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11
Q

what is required for a substance to absorb visible light?

A

there must be room for an electron in one orbital to be excited into another orbital, and the difference between their energy levels must correspond to a frequency of visible light

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12
Q

what does the aufbau principle state?

A

D- block elements fill up 4s first then 3d

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13
Q

which 2 elements are exceptions to the aufbau principle?

A

chromium
copper
they have 1 electron in 4s and the rest in 3d

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14
Q

which sub shell fills up and loses electrons first?

A

4s

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15
Q

which oxidation states have we seen copper in?

A

+1
+2

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16
Q

which d-block ions formed colourful compounds?

A

ones with a
part full
part empty
d orbitals

Differences in energy between orbitals

17
Q

what is the definition of transition metals?

A

metals which form stable ions with partially filled d orbitals

18
Q

what are ligands?

A

they can be a molecule or an ion
they must have a lone pair
they form dative covalent(coordinate) bonds with transition metal ions

19
Q

what is the number of dative covalent bonds to each metal ion known as?

A

coordination number

20
Q

what does cisplatin contain?

A

chloride ions
ammonia molecules

21
Q

complex ions can:

A

contain more than one type of ligand
involve no covalent bonds
involve no ionic bonds
have a positive overall charge
have a neutral overall charge
have a negative overall charge

22
Q

what does the (II) represent?

A

the oxidation state of the metal ion

23
Q

what happens if there are two identical ligands next to each other in a square planar complex ion?

A

we give them the letter z
or the word cis
as a prefix

24
Q

what happens if the two identical ligands are separated in a square complex ion?

A

we give them the letter E
the word trans
asa prefix