Transition elements Flashcards

1
Q

Transition element definition

A

And block element that forms one or more stable ions with an incomplete d subshell

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2
Q

Electronic configuration of scandium with [Ar]

A

3d1 4s2

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3
Q

Electronic configuration of Zinc with [Ar]

A

3d10 4s2

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4
Q

Chromium configuration

A

1s2 2s2 2p6 3s2 3p6

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5
Q

Copper

A

1s2 2s2 2p6 3s2 3p6 3s2 3p6 3d10 4s1

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6
Q

Features of transition elements

A
  • Variable oxidation states
  • Colorful compounds
  • Used as catalysts
  • Complex ions/compounds
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7
Q

Why do they have variable oxidation states

A
  • similarity in the energy of the 3d & 4s atomic orbitals
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8
Q

Why does an element have a have a - as maximum oxidation state?

A

It involves all of the 4s and 3d electrons in the atom

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9
Q

Why aren’t zinc and scandium transition element

A

Scandium has no electron fully satisfy the definition of transition elements
Zinc has a a completely full 3d subshell

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10
Q
A
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11
Q
A
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12
Q

Stability constant definition

A

The equilibrium constant for the formation of a complex ions in a solvent from its constituent ions or molecules

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13
Q

Ligand

A

A molecule or ion with one or more lone pairs of electrons which form dative covalent bonds to central transition element atom or ion.

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14
Q

Complex ion

A

A central transition metal ion surrounded by ligands, bonded to the central ion by dative covalent bonds.

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15
Q

Coordination number

A

No. of dative bonds formed by a ligand with a transition metal ion in a complex.

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16
Q

Bidentate ligand

A

A ligand that forms two dative bonds with a transition metal ion in a complex.

17
Q

Monodentate ligand

A

A ligand forming one dative bond with a transition metal ion in a complex.