topic two Flashcards

1
Q

describe the structure of metals?

A

giant structure
metal ions in layers
delocalised electrons

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2
Q

explain why polymers have higher melting points relative to substances made of small molecules?

A

they have much larger molecules
so stronger intermolecular forces
which require more energy to overcome

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3
Q

give two typical properties of substances made of small molecules?

A

low melting and boiling points
do not conduct electricity

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4
Q

explain why diamond is hard?

A

it has a giant covalent structure
it has strong covalent bonds between atoms
which are hard to break

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5
Q

explain why larger molecules have higher melting and boiling points than smaller ones?

A

they have stronger intermolecular forces
which require more energy to overcome

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6
Q

describe what happens to electrons in ionic bonding?

A

they are transferred from one atom to another

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7
Q

describe the structure of graphene?

A

one layer of graphite

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8
Q

explain how graphite conducts electricity, reference its structure and bonding?

A

each carbon atom has three bonds only
there is therefore one delocalised electron per carbon atom
the delocalised electrons are free to carry charge through the graphite

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9
Q

three main types of substances formed from covalently bonded atoms?

A

small molecules
very large molecules
and giant covalent structures

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10
Q

explain why ionic substances do not conduct electricity when solid?

A

because the ions are not free to move, so charge cannot flow

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11
Q

typical properties of pure metals?

A

high melting and boiling points
malleable
good conductors of electricity
good conductors of thermal energy

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12
Q

describe the structure of substances consisting of small molecules?

A

small molecules made up of atoms held together by strong covalent bonds
weak intermolecular forces act between the molecules

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13
Q

explain why ionic substances have high melting points?

A

there is a strong electrostatic force of attraction between oppositely charged ions which requires a lot of energy to break

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14
Q

explain why non metals do not form ionic bonds with each other?

A

non metal ions form negative charges, so would repel

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15
Q

explain why metals are good conductors of thermal energy?

A

delocalised electrons can move through the metal and transfer energy

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16
Q

two limitations of dot and cross diagram for ionic bonding?

A

it has only two ions and therefore does not show the giant structure

it does not show the three dimensional nature of the structure

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17
Q

3 examples of substances that consist of small molecules?

A

oxygen, water, ammonia

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18
Q

structure formed when metals and non metals react?

A

giant ionic structure

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19
Q

two properties of ionic susbtances?

A

high melting and boiling points
only conduct electricity when molten or in solution

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20
Q

explain why graphite can act as a lubricant?

A

there are no covalent bonds between the layers
so they are free to slide over each other

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21
Q

describe structure of a giant ionic lattice?

A

a 3d network of alternating positive and negative ions held together by the electrostatic force of attraction

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22
Q

how many bonds does each carbon atom have in diamond?

A

four

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23
Q

explain why buckminsterfullerene can be used as a lubricant?

A

the molecules have a spherical shape so can roll over each other

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24
Q

two limitations of ionic bonding structure diagram? NOT BALL AND STICK

A

ions do not actually touch
does not show electrons

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25
3 properties of graphene?
high melting point strong conducts electricity
26
explain why diamond does not conduct electricity?
the atoms do not have an overall charge it does not have delocalised electrons so charge cannot flow
27
structure of typical alloy?
metallic structure with atoms of different metals or carbon mixed in
28
3 examples of substances with a giant covalent structure?
diamond, silicon dioxide and graphite
29
explain why ionic substances conduct electricity in solution?
because the ions are free to move, SO CHARGE CAN FLOW
30
explain why simple molecular substances have low melting points?
weak intermolecular forces require little energy to overcome
31
explain in terms of electrons what occurs when magnesium reacts with oxygen to form magnesium oxide?
2 electrons are transferred from a magnesium atom to an oxygen atom the ions have full outer shells the ions are then attracted to each other by the electrostatic force of attraction
32
three uses of nanotubes?
nanotechnology electronics materials
33
relationship between size of a molecules and strength of its intermolecular forces?
larger a molecule, stronger its intermolecular forces
34
explain in terms of electrons what occurs when lithium reacts with oxygen to form lithium oxide?
2 lithium atoms transfer one electron each to one atom of oxygen the ions have full outer shells the ions are then attracted to each other by the electrostatic force of attraction
35
explain why substances consisting of small molecules do not conduct electricity?
the molecules do not have an overall electric charge so charge cannot flow
36
describe the structure of graphite?
each carbon atom forms three covalent bonds with three other carbon atoms the atoms form layers made of hexagonal rings
37
name three properties of diamond?
high melting and boiling points does not conduct electricity very hard
38
give two uses of graphene?
electronics and composites
39
explain in terms of electrons what occurs when magnesium reacts with chlorine to form magnesium chloride?
one magnesium atom transfers one electron to one chlorine atom, and another electron to a second chlorine atom. the ions have full outer shells the ions are then attracted to each other by the electrostatic force of attraction
40
explain why alloys can be harder than pure metals?
they have atoms of different sizes which distort the layers of the structure and prevent them from sliding over each other easily
41
explain why ionic substances conduct electricity when molten?
because ions are free to move and carry charge
42
explain why pure metals have high melting and boiling points?
strong metallic bonds between metal ions are delocalised electrons require a lot of energy to overcome
43
when a substance consisting of small molecules is melted or boiled, identify the forces that are overcome?
intermolecular forces NOT COVALENT BONDS
44
explain why diamond has a high melting and boiling point?
it has a giant covalent structure it has strong covalent bonds between atoms which require a lot of energy to overcome
45
explain why metals are good conductors of electricity?
delocalised electrons can move through the metal and carry charge
46
group 8 forms ion, charge?
1-
47
structure that is made of billions of atoms covalently bonded together?
giant covalent structure
48
typical state that substances made of small molecules are at room temp?
liquid or gas
49
explain why pure metals are malleable?
layers of metal ions are free to slide over each other
50
structural features that gives nanotubes their special properties?
a high length to diameter ratio
51
group 7 forms ion, state charge?
2-
52
structure of fullerenes?
molecules made of rings of carbon atoms with hollow shapes
53
two limitations of ball and stick for ionic bonding?
chemical bonds are not physical things like sticks it does not show electrons
54
structure of nanotubes?
cylindrical fullerenes
55
4 uses of nanoparticles?
nanomedicine nanoparticles in electrical circuits silver nanoparticles for antibacterial properties catalysts
56
how are nanoparticles used in nanomedicine?
fullerenes deliver drugs directly to the insider of cells, so tiny
57
how are nanoparticles used in electrical circuits?
some of them conduct electricity, so can theoretically make tiny computer chips
58
how are nanoparticles used in silver nanoparticles for antibacterial properties?
infuse them into surgical masks, wound dressings like plasters to kill bacteria
59
how are nanoparticles used in catalysts?
exposed SA is important, need much less nanoparticles in materials than bigger particles
60
evaluate the use of nanoparticles in suncream?
- YES more effective at protecting out skin from harmful UV rays because they provide better skin coverage - NO not clear if nanoparticles can get into out bodies, and whether they could be damaging our cells if they do - NO don't know what happens to them once washed into sea- possible they could be damaging the environment
61