Topic 8: proton transfer reactions Flashcards

1
Q

what are bronsted-lowry acids?

A

proton donors

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2
Q

what are bronsted-lowry bases?

A

proton acceptors

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3
Q

what is a conjugate acid-base pair?

A

two species that differ by a proton

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4
Q

what are amphiprotic species?

A

act as both a bronsted-lowry acid and base

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5
Q

what is an example of an amphiprotic species?

A

water

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6
Q

what does the pH scale measure?

A

how acidic or basic a substance is

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7
Q

what is the pH equation using (H+)?

A

pH = -log(H+)

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8
Q

what is the equation for concentration of H+ ions?

A

(H+) = 10^-pH

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9
Q

what happens to concentration when the the pH unit is changed by one?

A

a ten times change in H+ concentraon

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10
Q

what ions does water dissociate into?

A

hydronium and hydroxide
or
hydrogen and hydroxide

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11
Q
A
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12
Q

what is the relationship between the concentrations of hydrogen and hydroxide ions when water dissociates?

A

they are equal to each other

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13
Q

what does the ionic product constant equation exclude and what should it look like?

A

excludes H2O
Kw = (H+)(OH-)

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14
Q

what is the value of Kw at 298 K?

A

1.00 x 10^-14

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15
Q

strong acids ____ dissociates in solution

A

completely

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16
Q

weak acids ____ dissociates in solution

A

partially

17
Q

what arrow is used to represent the dissociation of a strong acid?

A

one way arrow

18
Q

what arrow is used to represent the dissociation of a weak acid?

A

two way arrow/ reversible arrow

19
Q

which side does equilibrium lie in the dissociation of strong acid equation and why?

A

right because there are more concentration of H+ ions and conjugate base

20
Q

which side does equilibrium lie in the dissociation of weak acid equation and why?

A

left because more acid is left

21
Q

what are examples of strong acids?

A

HCl, HNO3, H3PO4 (all numbers are subscripts)

22
Q

stronger acids create ____(weaker/stronger) conjugate base.

A

weaker

23
Q

what are the methods of distinguishing between weak and strong acids/bases?

A
  • electrical conductivity: stronger acid = higher conductivity because more mobile ions
  • Rate of reaction with active metals: higher conductivity = faster rate because higher conc. of H+ (only for acids)
  • pH level
24
Q

what does acid + metal hydroxide produce?

A

salt + water

25
Q

what does acid + metal oxide produce?

A

salt + water

26
Q
A
26
Q

what does acid + metal carbonate produce?

A

salt + water + carbon dioxide