Topic 8: proton transfer reactions Flashcards
what are bronsted-lowry acids?
proton donors
what are bronsted-lowry bases?
proton acceptors
what is a conjugate acid-base pair?
two species that differ by a proton
what are amphiprotic species?
act as both a bronsted-lowry acid and base
what is an example of an amphiprotic species?
water
what does the pH scale measure?
how acidic or basic a substance is
what is the pH equation using (H+)?
pH = -log(H+)
what is the equation for concentration of H+ ions?
(H+) = 10^-pH
what happens to concentration when the the pH unit is changed by one?
a ten times change in H+ concentraon
what ions does water dissociate into?
hydronium and hydroxide
or
hydrogen and hydroxide
what is the relationship between the concentrations of hydrogen and hydroxide ions when water dissociates?
they are equal to each other
what does the ionic product constant equation exclude and what should it look like?
excludes H2O
Kw = (H+)(OH-)
what is the value of Kw at 298 K?
1.00 x 10^-14
strong acids ____ dissociates in solution
completely
weak acids ____ dissociates in solution
partially
what arrow is used to represent the dissociation of a strong acid?
one way arrow
what arrow is used to represent the dissociation of a weak acid?
two way arrow/ reversible arrow
which side does equilibrium lie in the dissociation of strong acid equation and why?
right because there are more concentration of H+ ions and conjugate base
which side does equilibrium lie in the dissociation of weak acid equation and why?
left because more acid is left
what are examples of strong acids?
HCl, HNO3, H3PO4 (all numbers are subscripts)
stronger acids create ____(weaker/stronger) conjugate base.
weaker
what are the methods of distinguishing between weak and strong acids/bases?
- electrical conductivity: stronger acid = higher conductivity because more mobile ions
- Rate of reaction with active metals: higher conductivity = faster rate because higher conc. of H+ (only for acids)
- pH level
what does acid + metal hydroxide produce?
salt + water
what does acid + metal oxide produce?
salt + water
what does acid + metal carbonate produce?
salt + water + carbon dioxide