Topic 7 Flashcards

1
Q

7.2​ ​Suggest​ ​practical​ ​methods​ ​for​ ​determining​ ​the​ ​rate​ ​of​ ​a​ ​given​ ​reaction

A

Rate​​ of​​ reaction ​​=​​​ amount ​​of​​ reactant​​ used ​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​Time
​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​Rate​​ of ​​reaction​​ = ​​​amount​​ of​​ product​​ formed ​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​Time
o Quantity​ ​of​ ​reactant​ ​or​ ​product​ ​can​ ​be​ ​measured​ ​by​ ​the​ ​mass​ ​in​ ​grams​ ​or by​ ​a​ ​volume​ ​in​ ​cm3​
Units​​ of​​ rate ​​of​​ reaction​​ may​​ be​​ given​​ as ​​g/s​​ or​​ cm3​/​s
o o
to​ ​measure​ ​reactant​ ​used:​ ​if​ ​the​ ​product​ ​is​ ​a​ ​gas,​ ​which​ ​will​ ​be​ ​given​ ​off, you​ ​can​ ​carry​ ​out​ ​the​ ​reaction​ ​on​ ​a​ ​set​ ​of​ ​weighing​ ​scales​ ​and​ ​measure how​ ​much​ ​mass​ ​is​ ​lost
to​ ​measure​ ​product​ ​formed:​ ​if​ ​the​ ​product​ ​is​ ​a​ ​gas,​ ​you​ ​can​ ​measure​ ​the volume​ ​of​ ​gas​ ​produced​ ​in​ ​a​ ​gas​ ​syringe

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2
Q

7.3 Explain how reactions occur when particles collide and that rates of
reaction are increased when the frequency and/or energy of collisions is
increased

A

Chemical​ ​reactions​ ​only​ ​occur​ ​when​ ​the​ ​reacting​ ​particles​ ​collide​ ​with​ ​enough energy,​ ​the​ ​minimum​ ​amount​ ​of​ ​energy​ ​required​ ​is​ ​called​ ​the​ ​activation​ ​energy.
● in​ ​order​ ​to​ ​increase​ ​the​ ​rate​ ​of​ ​a​ ​reaction,​ ​you​ ​need​ ​to​ ​increase​ ​the frequency/energy​ ​of​ ​collisions,​ ​so​ ​that​ ​more​ ​of​ ​them​ ​reach​ ​the​ ​activation​ ​energy
● this​ ​can​ ​be​ ​done​ ​by:​ ​increasing​ ​temperature,​ ​pressure,​ ​concentration,​ ​surface area​ ​or​ ​by​ ​using​ ​a​ ​catalyst

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3
Q

7.3 Explain how reactions occur when particles collide and that rates of
reaction are increased when the frequency and/or energy of collisions is
increased

A

● Chemical​ ​reactions​ ​only​ ​occur​ ​when​ ​the​ ​reacting​ ​particles​ ​collide​ ​with​ ​enough energy,​ ​the​ ​minimum​ ​amount​ ​of​ ​energy​ ​required​ ​is​ ​called​ ​the​ ​activation​ ​energy.
● in​ ​order​ ​to​ ​increase​ ​the​ ​rate​ ​of​ ​a​ ​reaction,​ ​you​ ​need​ ​to​ ​increase​ ​the frequency/energy​ ​of​ ​collisions,​ ​so​ ​that​ ​more​ ​of​ ​them​ ​reach​ ​the​ ​activation​ ​energy
● this​ ​can​ ​be​ ​done​ ​by:​ ​increasing​ ​temperature,​ ​pressure,​ ​concentration,​ ​surface area​ ​or​ ​by​ ​using​ ​a​ ​catalyst

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4
Q

7.4 Explain the effects on rates of reaction of changes in temperature,
concentration, surface area to volume ratio of a solid and pressure (on
reactions involving gases) in terms of frequency and/or energy of collisions
between​ ​particles

A

● Increasing​ ​the​ ​temperature​ ​increases​ ​the​ ​rate​ ​of​ ​reaction.​ ​As increasing​ ​temperature​ ​increases​ ​the​ ​kinetic​ ​energy​ ​of particles,​ ​so​ ​they​ ​collide​ ​more​ ​frequently​ ​and​ ​energetically.
● Increasing​ ​pressure​ ​in​ ​reacting​ ​gases​ ​increases​ ​the​ ​rate​ ​of​ ​reaction,​ ​as​ ​it increases​ ​the​ ​number​ ​of​ ​particles​ ​in​ ​a​ ​given​ ​volume​ ​so​ ​increases​ ​the​ ​frequency of​ ​collisions.
● Increasing​ ​concentration​ ​of​ ​reacting​ ​solutions​ ​increases​ ​the​ ​rate​ ​of​ ​reaction,​ ​as​ ​it increases​ ​the​ ​number​ ​of​ ​particles​ ​in​ ​a​ ​given​ ​volume​ ​and​ ​so​ ​increases​ ​the frequency​ ​of​ ​collisions.
● Increasing​ ​the​ ​surface​ ​area​ ​of​ ​solid​ ​reactants​ ​increases​ ​the​ ​rate​ ​of​ ​reaction,​ ​as​ ​it increases​ ​the​ ​frequency​ ​of​ ​collisions​ ​so​ ​increases​ ​the​ ​rate​ ​of​ ​reaction

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5
Q

Describe a catalyst as a substance that speeds up ROR

A

Catalysts​ ​are​ ​substances​ ​that​ ​speed​ ​up​ ​chemical​ ​reactions​ ​without​ ​being changed​ ​or​ ​used​ ​up​ ​during​ ​the​ ​reaction.​ ​They​ ​are​ ​the​ ​same​ ​and​ ​have​ ​the​ ​same mass​ ​at​ ​the​ ​end​ ​of​ ​the​ ​reaction.

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6
Q

Explain how the addition of a catalyst increase ROR

A

Catalysts​ ​decrease​ ​the​ ​activation​ ​energy;​ ​this increases​ ​the​ ​proportion​ ​of​ ​particles​ ​with​ ​energy​ ​to react,​ ​leading​ ​to​ ​more​ ​frequent​ ​successful​ ​collisions and​ ​so​ ​an​ ​increased​ ​rate​ ​of​ ​reaction
● Catalysts​ ​lower​ ​the​ ​activation​ ​energy​ ​by providing​ ​a​ ​different​ ​pathway​ ​for​ ​a​ ​chemical​ ​reaction that​ ​has​ ​a​ ​lower​ ​activation​ ​energy.

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7
Q

Recall that enzymes are biological catalyst

A

Enzymes​ ​act​ ​as​ ​catalysts​ ​in​ ​biological​ ​systems
● Yeast​ ​is​ ​the​ ​enzyme​ ​used​ ​in​ ​the​ ​production​ ​of​ ​ethanol​ ​as​ ​it​ ​is​ ​fermented​ ​from
sugars,​ ​ethanol​ ​is​ ​in​ ​alcoholic​ ​drinks

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