Topic 5 - Energy changes Flashcards
What is the conservation of energy principle?
Energy is conserved in chemical reactions. The amount of energy in the universe at the end of a chemical reaction is the same as before the reaction takes place
What is an exothermic reaction? Give examples.
A reaction where energy is transferred to the surroundings so that the surrounding temperature increases - combustion, oxidation reactions and neutralisation reactions. Negative sign of energy change
What is an endothermic reaction? Give examples.
A reaction where the energy is taken in from the surroundings so the surroundings temperature decreases - thermal decomposition, reaction of citric acid and sodium hydrogencarbonate. Negative sign of energy change
What is activation energy?
minimum amount of energy that particles need to react
what is a reaction profile?
A graph which shows the relative energies of reactants and products, as well as activation energy of the reaction
What occurs in a chemical reaction in terms of bond energies? Describe exothermic and endothermic reactions in terms of bond breaking/forming
Energy is supplied to break bonds and energy is released when bonds are made
exothermic- energy released from forming bonds is greater than that needed to break the bonds
endothermic- energy needed to break bonds is greater than energy released making them
What is the equation to find enthalpy change in terms of bond energies?
energy of reaction = sum of bonds broken - sum of bonds made
What is a cell?
A cell is composed of two electrodes dipped in an electrolyte solution. It produces electricity from a chemical reaction
What is a battery?
A battery consists of two or more cells connected in series
What determines the voltage obtained from a cell?I
Identities of metals used as electrodes and the identity and concentration of an electrolyte
State the advantages and disadvantages of using cells and batteries
+ more cheap or less cheap, some are rechargeable, a convenient source of electrical energy
- harmful chemicals
Describe rechargeable and non-chargeable cells
Rechargeable- chemical reactions are reversed when an external current is supplied
Non-rechargeable- reactants are used up, cannot be recharged
What is a fuel cell?
Fuel cells are supplied by fuel and oxygen to oxidise the fuel to generate electricity
What is the overall reaction in a hydrogen fuel cell? What are the half equations?
cathode: 2H2 = 4H+ + 4e-
Anode: O2 + 4H+ + 4e- = 2H2O
Overall: 2H2 + O2 = 2H2O
what are the advantages and disadvantages of hydrogen fuel cells?
advantages: no pollutants, no recharging
Disadvantages: flammable, H2 difficult to store, fossil fuel production, toxic chemicals, expensive production of H2 by electrolysis
