Topic 5 Flashcards
What is the Hamiltonian operator?
It is the total energy of the system.
Ĥ = T̂ + V̂
What is the eigenvalue equation?
Ôu(x)=λu(x)
where Ô is a linear operator
u(x) is the eigenfunction
λ is the eigenvalue
What is the relationship between eigenvalues
We assume that u(x) denote a set of normalised to unity eigenfunctions
The eigenfunctions corresponding to different eigenvalues , are mutually orthonormal meaning that
∫(∞ to−∞)uₙ∗(x)uₘ(x)dx=
1 when n=m
0 when n≠m
The equation equals to the Kronecker delta: δnm = 1 when n=m, and 0 when
n≠m
How can you write arbitrary solutions in abstract space?
As a sum of basis functions as you can take any function
u(x) that obeys the same boundary condition as the uₙ(x) can be expressed as
u(x) =∑ₙaₙuₙ(x) where
aₙ=∫(∞ to−∞)uₙ∗(x)u(x)dx=
aₙ – the coefficients of expansion (or probability amplitudes)