Topic 5 Flashcards

1
Q

What is the Hamiltonian operator?

A

It is the total energy of the system.

Ĥ = T̂ + V̂

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2
Q

What is the eigenvalue equation?

A

Ôu(x)=λu(x)
where Ô is a linear operator
u(x) is the eigenfunction
λ is the eigenvalue

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3
Q

What is the relationship between eigenvalues

A

We assume that u(x) denote a set of normalised to unity eigenfunctions

The eigenfunctions corresponding to different eigenvalues , are mutually orthonormal meaning that

∫(∞ to−∞)uₙ∗(x)uₘ(x)dx=
1 when n=m
0 when n≠m

The equation equals to the Kronecker delta: δnm = 1 when n=m, and 0 when
n≠m

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4
Q

How can you write arbitrary solutions in abstract space?

A

As a sum of basis functions as you can take any function
u(x) that obeys the same boundary condition as the uₙ(x) can be expressed as
u(x) =∑ₙaₙuₙ(x) where
aₙ=∫(∞ to−∞)uₙ∗(x)u(x)dx=
aₙ – the coefficients of expansion (or probability amplitudes)

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