Topic 5 Flashcards

1
Q

What is energy moved around by?

A

chemical reactions

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2
Q

What do chemicals store?

A

a certain amount of energy and different chemicals store different amounts

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3
Q

What happens if the products of a reaction store less energy than the original reactants?

A

the excess energy was transferred to the surroundings during the reaction

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3
Q

What happens if the products of a reaction store more energy than the original reactants?

A

they must have taken in the difference in energy between the products and reactants from the surroundings during the reaction.

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4
Q

Why does the overall amount of energy in a reaction not change?

A

because energy is conserved in reactions - it can’t be created or destroyed, only moved around. This means the amount of energy in the universe always stays the same.

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5
Q

What happens to heat in an exothermic reaction?

A

heat is given out

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6
Q

What is an exothermic reaction?

A

one which transfers energy to the surroundings, usually by heating. This is shown by a rise in temperature

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7
Q

Give examples of an exothermic reactions.

A

-combustion (burning fuels) this gives out a lot of energy so it’s very exothermic.
-neutralisation reactions
-many oxidation reactions

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8
Q

What are some everyday uses of exothermic reaction?

A

-some hand warmers use the exothermic oxidation of iron in air with a salt solution catalyst to release energy
-self heating cans of hot chocolate and coffee also rely on exothermic reactions between chemicals in their bases

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9
Q

What happens to heat in an endothermic reaction?

A

heat is taken in

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10
Q

What is an endothermic reaction?

A

is a reaction which takes in energy from the surroundings. This is shown by a fall in temperature.

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11
Q

Are exothermic or endothermic reactions more common?

A

exothermic reactions are more common

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12
Q

What are some examples of endothermic reaction?

A

-the reaction between citric acid and sodium hydrogen carbonate
-thermal decomposition

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13
Q

What are some everyday uses of endothermic reactions?

A

sports injury packs - the chemical reaction allows the pack to become instantly cooler without having to put it in a freezer.

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14
Q

What is needed to break bonds and is breaking bonds endothermic or exothermic?

A

Energy must be supplied to break existing bonds - so it’s an endothermic process

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15
Q

What happens when bonds are made and is making bonds endothermic or exothermic?

A

Energy is released when new bonds form - so is an exothermic process

16
Q

What is the formula for the overall energy change?

A

overall energy change = energy required to break bonds -energy released by forming bonds

17
Q

What is an electrochemical cell?

A

a basic system made up of different electrodes in contact with electrolyte.

18
Q

What are electrode usually?

A

metals as they must be able to conduct electricity

19
Q

What is an electrolyte?

A

An electrolyte is a liquid that contains ions which react with the electrodes

20
Q

How can a simple cell be made?

A

A simple cell be made by connecting two different metals in contact with an electrolyte.

21
Q

What does the voltage produced by a cell depend on?

A

The voltage produced by a cell is depends on the type of electrode and electrolyte

22
Q

What happens in non-rechargeable cells and batteries when one of the reactants has been used up? Give an example of a non-rechargeable battery.

A

The chemical reactions stop when one of the reactants has been used up. Alkaline batteries are non-rechargeable.

23
Q

Why can rechargeable cells and batteries can be recharged?

A

Because the chemical reactions are reversed when an external electrical current is supplied.

24
What do fuel cells use to produce electrical energy?
fuel and oxygen
25
What is a fuel cell?
A fuel cell is an electrical cell that's supplied with fuel and oxygen and uses energy from the reaction between them to produce electrical energy efficiently.
26
What happens when fuel enters the fuel cell?
it becomes oxidised and sets up a potential difference within the cell
27
Give an example of a different type of fuel cell.
Hydrogen-Oxygen fuel cells. This fuel cell combines hydrogen and oxygen to produce nice clean water and release energy
28
What type of reaction does a hydrogen-oxygen fuel cell involve?
a redox reaction
29
What are the electrolyte and electrodes often in a hydrogen-oxygen fuel cell?
The electrolyte is often an acid such as phosphoric acid. The electrodes are often porous carbon with a catalyst.
30
In a hydrogen-oxygen fuel cell what goes into the anode compartment and what goes into the cathode compartment?
Hydrogen goes into the anode compartment and oxygen goes into the cathode compartment.
31
What is oxidation in terms of a hydrogen-oxygen fuel cell? What is the half equation that shows this?
At the -ve electrode (the anode), hydrogen loses electrons to produce H+ ions. H ---> 2H+ + 2e- 2
32
What is reduction in terms of a hydrogen-oxygen fuel cell? What is the half equation that shows this?
At the +ve electrode (the cathode), oxygen gains electrons from the cathode and reacts with H+ ions from the acidic electrolyte to make water. O + 4H+ + 4e- ----> 2H O 2 2
33
What is the overall reaction in a hydrogen-oxygen fuel cell?
Hydrogen plus oxygen gives water 2H + O ---> 2H O 2 2 2
34
How are fuel cells better than batteries in vehicles?
-Fuel cell vehicles don't produce as many pollutants as other fuels. Electric vehicles don't produce many pollutants either but their batteries are more polluting to dispose than fuel cells because they're made from highly toxic metal compounds. -Batteries in electric vehicles are rechargeable but there's a limit to how many times they can be recharged before they need replacing -Batteries are more expensive to make than fuel cells -Batteries also store less energy than fuel cells and so would need to be recharged more often which can take a long time
35
What are some disadvantages of using hydrogen fuel cells?
-Hydrogen is a gas, so it takes up loads more space to store than a rechargeable battery. -Hydrogen is explosive when mixed with air so it's hard to store safely