topic 4 (majority - just whats needed for mocks) Flashcards
oxidation
gain of oxygen, loss of electrons
reduction
loss of oxygen, gain of electrons
combustion
involve oxidation
- they are always exothermic
reactivity series
list of metals in order of reactivity,
the least reactive are most resistant to oxidation
most reactive easily lose their electrons to form cations
reactivity of metals based on how they react with acid
the more reactive the metal the faster the reaction with the acid will go
very reactive metals will fizz vigorously, less reactive will bubble a bit
you can show hydrogen is forming using a burning splint test. the louder the squeaky pop the more hydrogen = more reactive
what is an ore
a rock which contains metals often chemically combined with other substances
a rock which contains enough metal to make it economically worthwhile - found in earth’s crust
displacement reactions
redox reactions
- more reactive metal is oxidised and less reactive metal is reduced
- more reactive metals displace less reactive ones
e. g cooper sulfate + iron - iron sulfate + copper
explain how some metals can be extracted
a metal can be extracted from its ore chemically by reduction using carbon. When the ore is reduced, oxygen is removed from it. The position of the metal in the reactivity series determines whether it can be extracted by reduction with carbon
reduction with carbon and reactivity series
metals higher than carbon in the reactivity series have to extracted using electrolysis (expensive)
metals below carbon in the reactivity series can be extracted by reduction using carbon. (iron oxide is reduced in a blast furnace to make iron)
this is because carbon can only take the oxygen away from metals which are less reactive than carbon itself is
electrolysis
- BREAKING DOWN OF A SUBSTANCE USING ELECTRCITY
- once the metal ore is melted an electric current is passed through it. Metal is discharged at cathode, non-metal at the anode
- expensive
- ## large amounts of electricity
biological methods to extract metal
bioleaching
phytoextraction
bioleaching
uses bacteria to separate metals from their ores. The bacteria get energy from the bonds between the atoms in the ore, separating out the metal. The leachate contains metal ions which can be extracted by electrolysis or displacement electrolysis with a more reactive metal
phytoextraction
involves growing plants in the soil that contains metal compounds. The plants can’t be used or get ride of the metal gradually build up in the leaves. The plants can be harvested, dried and burned in a furnace. The ash contains metal compounds from which the metal can be extracted by electrolysis or displacement reactions
forward reaction
exothermic A reaction that transfers energy from reactants to the environment. Increase temperature
The position of equilibrium will shift in the endothermic direction. This means that the amount of products generated by the endothermic reaction will increase.
backwards reaction
endothermic A reaction that transfers energy from the environment to reactants Increase temperature
The position of equilibrium will shift in the endothermic direction. This means that the amount of products generated by the endothermic reaction will increase.