topic 4 extrating metals and equilibrium Flashcards

1
Q

what is oxidization and reduction

A

The reaction with or addition of oxygen.
Reduction can be the removal of oxygen

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2
Q

most to least reactive metals

A

pottasium, sodium, calcium, magnesium, aluminium, carbon, zinc, iron, hydrogen, copper, silver, gold

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3
Q

trend from the series

A

the metals at the top are the most reactive- they easily loose their electrons to form cations (positive ions). They oxidise easily

the metals at the bottom are the least reactive- they don’t give up their electrons easily, they are more resistant to oxidisation.

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4
Q

how do metals react with dilute hydrochloric acid

A

The more reactive the metal the faster the reaction with acid will go
the more reactive the more bubbles are produced and it fizzes more.
speed is indicated by the rate the hydrogen bubbles are given off

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5
Q

trends

A
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6
Q

test for hydrogen results on metals

A

Magnesium- loud squeaky pops
aluminium- fair old squeaky pop
zinc- quiet squeaky pop
iron- very quiet squeaky pop
copper- no reaction

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7
Q

how do metals react in water

A

more reactive metals like pottasium, sodium, lithium and calcium will react vigorously while less reactive metals like magnessium, iron and zinc will not react much with water

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8
Q

how is displacement reaction a redox reaction

A

a more reactive element reacts to take the place of a less reactive metal . More reactive metal loses electrons while less reactive metal gains electrons.
more reactive metal is OXIDISED while less reactive metal is REDUCED

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9
Q

what is metal extracted from

A

ores found in earth’s crust

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10
Q

where are unreactive metals found

A

found in earth’s crust as uncombined elements

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11
Q

what are the ways to extract metals from ores

A

heating with carbon, electrolysis

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12
Q

why is one or the other used

A

Heating with carbon economically worthwhile but is only able to be used on less reactive elements like gold and zinc.
electrolysis- Is able to be used on any element but takes a lot of energy so is economically unrealistic.

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13
Q

name other alternative biological methods of extracting

A

bioleaching and phytoextraction

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14
Q

what is bioleaching

A

Uses bacteria to separate metals from their ores. The bacteria gets energy from the bonds between the ore, separating out the metal in the process. The leachate (solution produced) contains metal ions.

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15
Q

what is phytoextraction

A

Plants growing in soil that contains metal compounds absorb the metals and they build up in the leaves. Plants are then burned. The ash contains metal compounds

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16
Q

what is the corelation with the resistance to oxidization and the metals position in the series

A

the lower down the metal the resistance is higher as they don’t give up their electron easily

17
Q

What are the advantages of recycling

A

1) Conserves resources and energy.
2) protects the environment
3) economic benefits

18
Q

how does recycling conserve resources and energy

A

1) extracting raw resources takes a lot of energy
2) fossil fuels are running out and using less energy conserves them
3) recycling saves energy as a small fraction of energy needed to extract and refine the materials form scratch
4) finite amount of raw material

19
Q

how does recycling protect environment

A

extracting materials, such as mines and deforestation damage nd destroy habitats
large amount of rubbish gets sent to landfill

20
Q

how does recycling have economic benefits

A

1) energy to extract meterial is expensive
2) metals that are expensive should be recycled
3) recycling creates many jobs
4) jobs created at every stage of process

21
Q

what is a life cycle of a product

A

looks at each stage of the process and life of a product. there are 4 stages Choice of material, manufacture, product use, disposal

22
Q

explain the life cycle stage choice of product

A

1)Metals have to be mined and extracted these processes take a lot of energy and cause pollution
2) raw material for chemical manufacturer comes from crude oil.

23
Q

explain the life cylce stage manufacture

A

1) manufacturing products take a lot of energy and other resources
2) cause pollution
3) waste products and disposal
4) waste can be recycled and turned into useful chemicals
5) needs water and don’t put polluted water back

24
Q

explain the life cycle stage- product use

A

1) paint gives off toxic fumes
2) burning fuels releases greenhouse gasses
3) fertilisers can leach into streams and rivers and euthanise the water

25
explain the life cycle stage- disposal
1) often disposed at landfill 2) pollute land and water 3) products may be incinerated
26
what does this symbol mean: ⇌
that the reaction is reversible (can be altered by changing conditions)
27
what is meant by a dynamic equilibrium
when the forward reaction of a reactant is equal to the backward reaction of the product Only possible in a closed system
28
what are the temperature conditions for the haber process
temperature 450- the higher the temperature the higher rate of reaction however equilibrium is needed to shift to exothermic direction by lowering temperature for higher yield so 450 is a compromise
29
what are the pressure conditions for the haber process
200 atmospheres- As we want to increase pressure for faster rate of reaction and higher yield. However it is expensive and dangerous to increase pressure
30
what catalyst is used for the Haber process
iron catalyst- increases rate of reaction
31
how is the position of a dynamic equilibrium changed by temperature
If you decrease the temperature, will move to exothermic direction (releases heat to environment). If you increase the temperature, will move in endothermic direction ( takes in heat from environment).
32
how is the position of the dynamic equilibrium changed by pressure?
Increase pressure, will move to side with fewer MOLES of gas to reduce pressure. decrease pressure, will move to side with more MOLES of gas to increase pressure.
33