Topic 4-Chemical Changes Flashcards

1
Q

How do you measure a pH of a solution?

A

An indicator is a dye that changes colour depending on whether its above or below a certain pH. It will gradually change colours over a broad range of pH. These are wide range indicators and they are useful for estimating pH.
A pH probe attached to a pH meter can measure pH electronically. The probe is placed in the solution you are measuring and the pH is given as a numerical value meaning it is more accurate than an indicator.

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2
Q

What happens to acids in aqueous solutions?

A

They ionise to produce hydrogen ions.

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3
Q

What happers to strong acids in water?

A

Such as hydrochloric acid ionise completely in water. All the acid particles dissociate to releass hydrogen ions.

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4
Q

What happens to weak acids in water?

A

They dont fully ionise so only a small proportion of acid particles dissociate to release hydrogen ions. The ionisation of a weak acid is a reversible reaction.

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5
Q

What is the pH a measure of?

A

The concentration

of hydrogen ions in the solution.

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6
Q

What does the concentration of an acid tell you?

A

How much acid there is in a certain volume of water.

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7
Q

What does acid strength tell you?

A

It tells you what proportion of the acid molecules ionise in water.

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8
Q

Describe the practical of making a salt from an insoluable base?

A

To make copper chloride you could mix hydrochloric acid and copper oxide.
Gently warm the dilute acid using a bunsen burner.
Add the copper oxide to the hydrochloric acid abit at a time until no more reacts. You will know it has been neutralised as even after stirring the excess solid would just sink to the bottom of the flask.
Then filter out the excess solid to get the salt solution.
To get the crystals of the salt gently heat the solution using a water bath or electric hester to evaporate some of the water then stop hesring and leave it to cool. Crystals of the salt should form which can be filtered out of the solution and the dried. (Crystallisation).

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9
Q

What is the order of the reactivity series?

A
Potassium
Sodium
Lithium
Calciun
Magesium
Carbon
Zinc
Iron
Hydrogen
Copper
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10
Q

Why are carbon and hydrogen in the reactivity series?

A

Metals less reactive than carbon can be extracted from there ores by reduction with carbon. Metals more reactive cant be extracted this way.
Metals more reactive than hydrogen will react with acids. Metals less reactive will not react with acids.

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11
Q

How can you indicate the speed of a reaction?

A

The rate that hydrogen bubbles are given off.

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12
Q

What metals will react with water?

A

Potassium
Sodium
Lithium
Calcium

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13
Q

What metals wont react with wated?

A

Zinc
Iron
Copper

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14
Q

What is the formation of a metal ore called?

A

Oxidation. There is a gain of oxygen.

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15
Q

What is the extraction of a metal called?

A

Reduction. There is a loss of oxygen.

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16
Q

How can metals be extracted using carbon?

A

Metals above carbon have to be extracted using electrolysis.
Metals below carbon in the reactivity series can be extracted by reduction using carbon.
For example iron oxide is reduced in a blast furnace to make iron. This is because carbon can only take oxygen away from metals which are less reactive than carbon itself.

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17
Q

What is the loss of electrons called?

A

Oxidation.

18
Q

What is the gain if electrons called?

A

Reduction.

19
Q

What is a redox reaction?

A

When reduction and oxidation happens at the same time.

20
Q

What happens in the redox reaction of a metal reacting with an acid? (Iron and sulphuric acid)

A

The iron atoms lose electrons to become positive iron ions. They are oxidised by hydrogen ions.
The hydrogen ions gain electrons to become hyrogen atoms. They are reduced by the iron atoms.

21
Q

What happens during the redox reaction ot halogen displacement reactions?

A

A more reactive halogen can displace a less reactive halogen from a salt solution.
The chlorine atoms gain electrons to become chloride ions. They are reduced by the bromide ions.
The bromide ions lose electrons to become bromide atoms. They are oxidised by chlorine atoms.

22
Q

What happens in metal displacement reactions?

A

A more reactive metal will displace a less reactive metal from its compound.

23
Q

What happens to the metal ion in a displacement reaction?

A

The metal ion gains electrons and is reduced.

24
Q

What happens to the metal atom in the displacement reaction?

A

It always loses electrons and is oxidised.

25
Q

What do ionic equations concentrate on?

A

Which substances were oxidised or reduced.

26
Q

Where will the positive ions move in electrolysis?

A

To the cathode and they will gain electrons.

27
Q

Where will the negative ions move in electrolysis?

A

It will move towards the anode and they will lose electrons.

28
Q

Why cant ionic solids be electrolysed?

A

As the ions are in fixed positions so they cant move.

29
Q

How can you use electeolysis of ionic solids to form elements?

A

The electrodes should be an inert material so they dont react with the electrolyte.
The positive metal ions are reduced to the element at the cathode.
The negative non metal ions are oxidised to the element at the carhode.

30
Q

How can metals be extracted from their ores usinf electrolysis?

A

If a metal is too reactive to be reduced with carbon then electrolysis is used to extract it. However it is expensive and alot of energy is needed to melt the ore and produce the required current.
The molten mixture of aluminium oxide contains free ions so it’ll conduct electricity.
The positive aluminium ions go to the negative electrode where they pick up three electrons and turn into neutral aluminium atoms and sink to the bottom of the electrolysis tank.
The negative oxygen atoms are attracted to the positive electrode where they each lose two electeons. The neutral oxygen atoms will combine to make oxygen molecules.

31
Q

What happens at the negative electrode during the extraction of an ore?

A

Metals form positive ions so they are attracted to the negative electrode.
So aluminium is produced at the negative electrode.

32
Q

What happens at the positive electrode during the extraction of an ore?

A

Non metals form negative ions so they sre attracted to the positive electrode.
So oxygen is produced at the positive electrode.

33
Q

What are in the electrolysis of aqueous solutions?

A

Ions from the ionic compound.
Hydrogen ions.
Hydroxide ions.

34
Q

What happens at the cathode during electrolysis of aqueous solutions?

A

It hydrogen ions and metal ions are present, hydrogen gas will be produced if the metal form a metal more reactive than hydrogen.
If the metal ions form a metal less reactive than hydrogen a solid layer of pure metal will be produced instead that will coat the cathode.

35
Q

What happens at the anode during electrolysis in aqueous solutions?

A

If hydroxide ions and halide ions are present molecules of chlorine, bromine or iodine will be formed.
If no halide ions are present then the hydroxide ions from the water will be discharged and oxygen gas will be formed.

36
Q

Describe what happens during the electrolysis of copper sulphate solution?

A

Copper is less reactive than hydrogen so at the cathode copper metal is produced and coats the electrode.
There arent any halide ions present so at the anode oxygen snd water are produced. The oxygen can be seen as bubbles.

37
Q

Describe what happens during the electrolysis of sodium chloride solution?

A

Sodium metal is more reactive than hydrogen. So at the cathode hydrogen gas is produced.
Chloride ions are present in the solution. So at the anode chlorine gas is produced.

38
Q

How do you know chlorine gas has been produced at the electrode?

A

It would bleach damp litmus paper white.

39
Q

How would you find out if hydrogen was produced at the electrode?

A

It would make a squeaky pop with a lighted splint.

40
Q

How do you know if oxygen is produced at the electrode?

A

It will relight a glowing splint.