Topic 4 Flashcards

1
Q

What is the general formula when a group 2 metal (M) reacts with water?

A

M + 2H20 –> M(OH)2 +H2

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2
Q

What is the trend in ionisation energy down group two

A

As you go down there is an extra electron shell so more shielding so electrons are further away from the nucleus which reduces electrostatic attraction therefore decreasing the ionisation energy

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3
Q

What is the general occasion when a group to metal (M) burns in oxygen

A

2M + O2 –> 2MO

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4
Q

What is the general equation when a group 2 metal (M) reacts with chlorine?

A

M+ Cl2 –> MCl2

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5
Q

General equation when a group 2 metal oxide (M) reacts with water

A

MO + H2O –> M(OH)2

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6
Q

General equation when a group 2 metal (M) hydroxides reacts with water?

A

M(OH)2 (s) —> M(OH)2 (l)

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7
Q

Reaction between group to metal oxide (M) reacts with dilute acid

A

MO + 2HCl –> MCl2 + H2O

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8
Q

General equation when a group two metal hydroxide (M) reacts with dilute acid?

A

M(OH)2 + 2HCl –> MCl2 + 2H2O

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9
Q

Why does thermal stability increase down a group?

A

As you go down the group the cations get bigger so there is less distortion by anions such as carbonates or nitrates this makes them more thermally stable

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10
Q

Which group is more thermally stable group 1 or group 2 and why?

A

Group 2 has a greater charge so there is greater distortion so less thermally stable therefore group one is more thermally stable

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11
Q

Group 1 carbonates are thermally stable but what is the exception

A

Lithium carbonate

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12
Q

Group 1 nitrates decomposes to form what

A

The metal nitrate and oxygen gas

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13
Q

Group 2 carbonates decompose to form what

A

The metal oxide and carbon dioxide gas

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14
Q

Group 2 nitrites decomposes to form what

A

The metal oxide, nitrogen dioxide, and oxygen

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15
Q

What colour is lithium in a flame test

A

Red

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16
Q

What colour is sodium in a flame test?

A

Orange/yellow

17
Q

What colour is potassium in a flame test

A

Lilac

18
Q

What colour is calcium in a flame test

A

Brick red

19
Q

What colour is Rubidium in a flame test

A

Red

20
Q

What colour is the caesium in a flame test

A

Blue

21
Q

What colour is strontium in a flame test

A

Crimson

22
Q

What colour is barium in a flame test

A

Green

23
Q

What colour is magnesium in a flame test

A

It doesn’t produce a colour

24
Q

Why does the flame tests produce different colours

A

Energy is absorbed from the flame as electrons move to higher energy levels. The colours of seen when the electrons fall back down to lower energy level is releasing energy in form of light

25
Q

Why do you halogens gets less reactive when you go down the group

A

The atoms become larger so electrons are further from the nucleus, there is also shielding. This makes it harder for large atoms to attract the electron they need.

26
Q

Explain the trend in melting and boiling points as you go down group 7

A

As you go down group 7 there is an increase in electron shells. This means there are more London forces so the melting and boiling points are higher to overcome the intermolecular forces

27
Q

What ions can chlorine displace

A

Bromide and iodide

28
Q

What is the equation when sodium hydroxide reacts with chlorine

A

2NaOH(Aq) + Cl2 (g) –> NaClO (Aq) + NaCl (Aq) + H2O (l)

29
Q

What is the general equation when halogen (X) reacts with a hot alkali?

A

3X2 + 6NaOH –> NaXO3 + 5NaX + 3H2O