Topic 25: Carbonyl Group Flashcards
Carbonyl group
C=O
Aldehyde
Contains carbonyl group on the end (hyde) (hidding on the end)
Ketone
Contains carbonyl group NOT on the end
Aldehyde nomenclature
alkanal
eg pronanal
butanal
Never numbers as always on end
Ketone nomenclature
alkanone
eg propanone
pentan-2-one
Number as can be anywhere in middle of chain
Aldehydes oxidise into
Carboxylic acids
Ketones oxidise into
Nothing… they don’t oxidise
Test for aldehyde/ ketone
Tollens reagent creates silver mirror when reacts with aldehyde, NOT ketones
Tollens reaction
[Ag(NH3)2]^+ reduced to Ag
Primary alcohol oxides to ____ oxides to ____
aldehyde - carboxylic acid
Reduced the otherway as well
Secondary alcohol oxidises to ____ oxides to ____
Ketone - NOTHING
Reduced the other way as well
Reducing agent of carbonyl group compounds
NaBH4
Sodium Tetrahydridoborate