Topic 2 - structure and bonding Flashcards
Define ionic bonding
Electrostatic forces of attraction between oppositely charged ions.
Properties of a GIANT IONNIC STRUCTURE
regular structure
neat rows of ions
cubic shape
giant repeating pattern
How to write ionic formulae
write out elements/molecules with their charges
swap them
move them to subscripts and divide as necessary to get simplest form.
Why are most ionic compounds soluble in water?
water is polar and has a strong attraction to the charged ions, which dissociate into it. Water breaks ionic bonds by hydrogen bonding.
When can ionic compounds conduct electricity and why?
When molten/dissolved in solution because ions are free to move and carry charge.
Why do ionic compounds have really high melting points?
Strong electrostatic forces of attraction require a lot of energy to overcome
Why are ionic compounds brittle?
when struck with a hammer, layers of ions slide so cations align with cations and the same with anions. This causes them to repel which in turn breaks the structure.
What determines the strength of ionic bonds?
Size of ion: smaller = stronger
charge density: greater = stronger
Define isoelectronic
Ions with the same number of electrons / electronic structure. E.g Na+, Mg2+ etc