Topic 2 - States Of Matter Flashcards
Describe the arrangement and movement of particles in solids
- Tightly packed together in a regular arrangement
- vibrate in fixed positions
Describe the arrangement and movement of particles in liquids
- close together but able to move past each other
- vibrate and move around each other
Describe the arrangement and movement of particles in gases
- Well separated with no regular arrangement
- Vibrate and move freely at high speeds
Compare the relative energies of particles in solids, liquids and gases
Particles in a solid have the least amount of energy and particles in a gas have the most energy
What does ‘ interconversion of state’ mean ?
When matter changes from one state to another due to changes in temperature or pressure
What are the names for the state changes from solid to liquid and vice versa ?
Solids to liquid = melting
Liquid to solid = fresszing
What are the names for the state changes from liquid to gas and vice versa?
Liquid to gas = evaporation
Gas to liquid = condensation
Describe the forces between particles in solids, liquids and gases
Solid- strong forced of attraction between particles which keeps them in their fixed positions
Liquids - weaker attractive forces than in solids
Gases - weakest intermolecular forces so particles are in random movement
How does a physical change differ from a chemical change ?
A physical change involves changes in the forces between particles . The particles themselves remain the same and the chemical properties remain the same.
A chemical change is different as it affects the chemical properties of the substance
True or false? Physical changes are relatively easy to reverse
True as no new product is formed
What is the term when describing when a solid changes straight into a gas?
Sublimation
Describe what happens in therms of particles , when a solid is heated and melts into a liquid
When heated, the particles absorb thermal energy which is converted into kinetic energy. The particles in the solid vibrate more. This causes the solid to expand until the structure breaks, and becomes a liquid
Describe what happens, in terms of particles, when a liquid is heated and evaporates into a gas
When heated, the particles in a liquid expand and some particles on the surface gain sufficient energy to overcome the intermolecular forces and evaporate. At the boiling point, all of the liquid particles gain enough energy to evaporate.
What is a mixture?
Contains 2 or more elements or compounds that are not chemically combined together.
The chemical properties of each substance in the mixture are unchanged
What is a pure substance ?
A single element or compound, not mixed with any other substance
How can you use melting point data to distinguish between pure substances and mixtures?
Pure substances have a sharp exact melting point whereas mixtures melt over a range of temperatures since they consist of several elements/ compounds
When is simple distillation used?
Used to separate a pure liquid from a mixture of liquid. Only works when the liquids have different boiling points
How can ethanol be separated from water?
Ethanol has a lower boiling point than water so can be separated from water by simple distillation
When is fractional distillation used to separate mixtures?
Used to separate all the elements / compounds in a mixture. These chemicals must have different boiling points
What is the difference between fractional and simple distillation?
Simple distillation only able to separate the liquid with the lowest boiling point from the mixture.
Fractional distillation separates all the chemicals in a mixture, using their boiling points
How does fractional distillation work?
- Oil is heated until it evaporates into the fractionating column.
- Vapours rise up the fractionating column and condense at the different fractions, depending on the relative boiling point of each substance.
What sort of mixtures can filtration be used to separate?
An insoluble substance from a solution
Describe how you separate an insoluble substance from a solution
- place filter paper in funnel
- pour the solution containing an insoluble substance through the funnel into a conical flask.
- The insoluble substance will collect on the filter paper and the solution will collect in the conical flask
When is the process of crystallisation used to separate a mixture?
To separate a soluble solid from a solution if the solid decomposes when heated.
How could you separate a soluble solid from a solution, if the solid decomposes when heated?
Crystallisation
- pour the solution into an evaporating basin and heat gently.
- When the crystals start to form, remove the dish from the heat and leave to cool
- Once cold, filter the crystals out of the solution and leave them in a warm place to dry.
What process can be used to identify substances in a mixture?
Chromatography
How does paper chromatography work to separate a mixture?
- the mobile phase ( solvent) moves through the stationary phase ( paper ) so anything dissolved in the mobile phase will move up the paper.
- compounds interact differently with each phase so will move different distances through the stationary phase meaning they will be separated
How can chromatography show the composition of a mixture?
Different colour substances in the mixture will separate as they have different solubilities in the solvent and will travel at different rates.
Why should pencil be used to draw the line along the bottom of the chromatography paper ?
It will not affect the experiment as it is insoluble in the solvent
Why should water in the beaker for paper chromatography be no deeper than 1cm ?
If it is deeper, it will wash away the substances placed on the line in the chromatography paper
Why should you use a lid when carrying out paper chromatography?
To prevent the solvent evaporating
How many spots will a pure substance produce on a chromatogram? How would this be different for an impure substance?
Pure substance produce one spot
An impure substance contains more than one compound so will produce more spots
What is an Rf value?
The Rf value is the ratio between the distance travelled by the dissolved substance and the distance travelled by the solvent
How do you calculate Rf value?
Distance travelled by substance/ distance travelled by solvent
When measuring the distance moved by a substance on the chromatography paper, where should measure between ?
Measure from the pencil baseline to the middle of the spot of the substance
How can you use chromatography to see if a certain substance is present in a mixture?
Run a pure sample of this substance alongside an unknown mixture
If the Rf value of the pure substance matches the value of one of the spots from the mixture, it is likely to be present.
True or false? Substances with a higher solubility in the solvent will travel further up the chromatography paper?
True
They will stay dissolved in the solvent ( mobile phase) for longer
How could you separate salt from a mixture of salt and sand?
Salt is soluble in water, sand isn’t
Add water to the mixture
Filter the solution to remove the insoluble sand
Evaporate the water to collect the salt crystals
How can liquids be separated if they have different densities?
If the liquids have different densities, they will naturally separate into two layers
To separate these layers, use a flask with a tap on the bottom. Open the tap to collect the bottom liquid ( has the highest density )
What does potable mean?
Safe to drink
How can waste and groundwater be made potable
- Sedimentation : large insoluble particles sink to the bottom after the water is left still for a while
- Filtration : removes small insoluble particles by passing the water through layers of sand and filters
- Chlorination : kills bacteria and microorganisms which are too small to be removed by filtration
How can sea water be made potable?
Distillation
1. Filter to removed insoluble particles
2. Boil
3. Cool and condense the water vapour
What issues surround the process of making seawater potable ?
- extremely expensive as it requires a lot of energy to boil large volumes of water
- waste water is toxic due to the high concentration of salt so must be disposed of carefullyb
What is deionised water?
Water that has had metallic ions ; such as copper or calcium) removed
Why is deionised water used in experimental analysis
Deionised water is used to prevent ions in the water interacting with the substances under analysis. If water wasn’t deionised, false psotive results may be produced