Topic 2 - Covalent bonding Flashcards
Covalent bonding
Electrostatic attraction between shared electrons and the positive nucleus
Dative bone
One atom donates 2 electrons to an atom or ion to form a bond
High electron density=
Stronger attractive force
Shorter bond
higher bond enthalpy
BP = 2
LP = 0
Linear
180 degrees
BP = 3
LP = 0
Trigonal planar
120 degrees
BP = 4
LP = 0
Tetrahedral
109.5 degrees
BP = 5
LP = 0
Trigonal Bipyramidal
90 & 120 degrees
BP = 6
LP = 0
Octahedral
9o degrees
BP = 3
LP = 1
Trigonal pyramidal
107 degrees
BP = 2
LP = 2
Bent
104.5
BP = 3
LP = 2
Distorted T
87.5 degrees
BP = 4
LP = 1
Seesaw
87 & 102 degrees
BP = 5
LP = 1
Square pyramidal
81.9 & 90 degrees
BP = 4
LP = 2
Square planar
90 degrees
Graphite
Each carbon boded 3 times
1 delocalised electron
Strong covalent bonds
Week forces between layers
Diamond & Silicon dioxide
Each carbon bonded 4 times into tetrahedral shape.
Tightly packed rigid arrangement allow heat to conduct well.
Many strong covalent bonds.
Graphene
1 layer of graphite.
Hexagonal carbon rings
delocalised electrons