Topic 2 - Bonding, structure and properties of matter Flashcards
What structure do Ionic compounds have?
A regular lattice structure
Describe the formation of ionic compounds?
- They have a structure called a giant ionic lattice
- The ions form a clsely packed regular lattice arrangement and there are very strong electromagnetic forces of attraction between oppositely charged ions, in all directions of the lattice
What properties do ionic compounds have?
- They all have high melting and boiling points due to the many strong bonds between the ions
- It takes a lot of energy to overcome this attraction
Can ionic compounds conduct electricity?
- When they are solid the ions are held in place, so the compounds can’t conduct electricity
- When ionic compounds melt, the ions are free to move and they’ll carry electric charge
- Some ionic compounds also dissolve in water. The ions separate and are all free to move in the solution, so they’ll carry electric charge.
What bonds do a metal and non metal form?
Ionic bonds
What bonds do non-metals form?
Covalent bonds
What bonds do metal atoms form?
Metallic bonds
Describe covalent bonding?
- When non-metal atoms bond together, they share pairs of electrons to make covalent bonds
- The positively charged nuclei of the bonded atoms are attracted to the shared pair of electrons by electrostatic forces, making covalent bonds very strong
- Atoms only share electrons in their outer shells
- Each single covalent bond provides one extra shared electron for each atom
What are simple molecular substances?
Simple molecular substances are made up of molecules containing a few atoms joined by covalent bonds
Common examples of simple molecular structures?
- Hydrogen
- Chlorine
- Oxygen
- Nitrogen
- Methane
What are properties of simple molecular structures?
- The atoms within the molecules are held together by very strong covalent bonds, but the intermollecular forces between the molecules are very weak
- To melt or boil a simple molecular compound you only need to break these feeble intermollecular forces, not break the covalent bonds
- This means they have very low melting and boiling points because the molecules are easily separated
- Most simple molecular structures are liquids or gases at room temperature
- As molecules get bigger, the strength of the intermollecular forces increases, so more energy is needed to break them, and the melting and boiling points increase
- Molecular compounds don’t conduct electricity as there are no fre electrons or ions
What are polymers?
Long chains of repeating units
Properties of polymers?
- In a polymer, lots of small units are linked together to form a long molecule that has repeating seactions
- All the atoms in a polymer are joined by strong covalent bonds
- The intermolecular forces between polymer molecules are larger than between simple covalent molecules, so more energy is needed to break them
- This means most polymers are solid at room temperature
- The intermolecular forces are still weaker than ionic or covalent bonds, so they generally have lower boiling points than ionic or giant molecular compounds
Describe giant covalent structures?
- In giant covalent structures, all the atoms are bonded to each other by strong covalent bonds
- They have very high melting and boiling points as lots of energy is needed to break the covalent bonds
- They dont have charged particles so they dont conduct electricity
Three examples of giant covalent structures?
- Diamond
- Graphite
- Silicon dioxide
What are allotropes?
- Allotropes are different structural forms of the same element in the same physical state
Describe diamond?
- Diamond is very hard
- Diamond is a giant covalent structure, made up of carbon atoms that each form four covalent bonds
- These strong covalent bonds take a lot of energy to break and give diamond a very high melting point
- It doesnt conduct electricty as there are no free ions or electrons
Describe graphite?
- In graphite, each carbon atom only forms three covalent bonds, creating sheets of carbon atoms arranged in hexagons
- There arent any covalent bonds between the layers - they are only held together weakly, so they are free to move over each other. This makes graphite soft and slippery, so it can be used as a lubricant
- Graphite has a high melting point - the covalent bonds in the layers need loads of energy to break
- It can conduct electricity. This is because only 3 out of each carbons 4 outer electrons are used in bonds, so each carbon atom has one delocalised electron.