Topic 2: Atomic Structure Flashcards

1
Q

What did Rutherford’s experiment consist of? What did Rutherford’s experiment determine?

A

Particle deflection. Determined that atoms are mostly empty space and that they have nuclei.

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2
Q

In nuclear notation, which numbers go where to represent atomic number, mass, and charge?

A

Mass number=upper left, atomic number=lower left, charge=upper right

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3
Q

Carbon 14 is a radioactive isotope. What is carbon 14 used for?

A

Carbon dating, cancer treatment

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4
Q

Cobalt-60 is a radioactive isotope. What is it used for? What type of radiation does it emit?

A

It emits gamma and is used to treat cancer, to stop an immune response to transplanted organs, and to sterilize foods.

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5
Q

Iodine-131 emits what kind of radiation? What is it used for?

A

Beta and gamma, to treat thyroid cancer.

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6
Q

Iodine-135 emits what kind of radiation and is used for what?

A

Emits gamma, treats prostate cancer and brain tumors.

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7
Q

Radioisotopes refers to…

A

radioactive isotopes

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8
Q

What do mass spectrometers do?

A

They measure the individual masses of atoms.

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9
Q

What are the 5 steps in the process of mass spectrometry?

A

Vaporization of the sample to separate particles, ionization of the atoms through e- bombardment to leave them with +1 charge, acceleration of ions thru a tube, deflection of ions through magnetic field, detection of ions measuring their location and # of particles.

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10
Q

Why is the deflection step so important in mass spectrometry?

A

Ions are deflected more or less depending on their absolute mass, charge, velocity, and the strength of the magnetic field. This step is shows as mass spectrum.

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11
Q

Describe the features of a mass spectrum graph.

A

Y-axis=percent abundance, x-axis=relative isotopic mass. You can determine the percent abundance of certain isotope groups. The number of peaks is the number of different isotopes.

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12
Q

How do you calculate relative atomic mass?

A

(isotopic mass 1 x %abundance as a decimal) + (isotopic mass 2 x %abundance as a decimal)…

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13
Q

What is the big important feature of the Bohr model?

A

It shows orbitals of differing energy as energy levels

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14
Q

What 4 concepts does the Bohr model support?

A

Electrons orbiting at fixed levels, orbitals further from nucleus are higher energy, electrons are quantized, electrons can only jump 1 orbital at a time.

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15
Q

What does it mean that electrons are quantized? What is ground state?

A

They can only be in one energy level or another, not in between. The ground state refers to their normal energy level.

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16
Q

What could Bohr not explain with his model?

A

Why only certain energy levels were allowed.

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17
Q

What causes emission spectra to be produced?

A

When e- emit photons as they transition from a higher to a lower energy level. Each transition corresponds to a specific wavelength and frequency.

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18
Q

Emission spectra can help scientists….

A

Identify an unknown element.

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19
Q

Line spectra only contain…

A

specific colors of visible light

20
Q

Spectra that are not line spectra are…

A

continuous, containing all colors

21
Q

What is proof that electrons exist in discrete energy levels?

A

The Hydrogen emission line spectrum

22
Q

What is the Balmer series?

A

When an e- drops from a higher energy level to n=2. Visible light is emitted.

23
Q

What is the Lyman series?

A

Electron transition to n=1. UV light emitted.

24
Q

What is the Paschen series?

A

Electron transition to n=3. IR light emitted.

25
Q

True or false: All electromagnetic waves travel at the same speed.

A

True. The speed of light is a constant.

26
Q

If all electromagnetic waves travel at the same speed, how can they be distinguished?

A

By their wavelengths (lamda symbol), which is the distance between two crests of the wave.

27
Q

What are the relationships between wavelength, frequency, and energy?

A

Higher frequency=higher energy=smaller wavelength because there are more waves per second. Lower frequency=lower energy=larger wavelength.

28
Q

What does the Electromagnetic spectrum show?

A

Range of all possible EM radiation frequencies.

29
Q

List the types of electromagnetic radiation in increasing order of energy.

A

Radio, microwave, IR, visible, UV, X-ray, gamma

30
Q

What does Heinsenberg’s Uncertainty Principle state?

A

It is impossible to exactly locate an electron

31
Q

What is an orbital?

A

A region with at least a 95% chance of finding an e-

32
Q

How many e- can ea. orbital hold?

A

2 max

33
Q

If there are 2 e- in one orbital, how do they spin?

A

Opposite spins.

34
Q

What is the Pauli exclusion principle?

A

Ea. orbital can hold 2e- max, with opposite spins.

35
Q

What is the Aufbau principle?

A

Electrons fill the lowest energy orbitals first.

36
Q

What is Hund’s Third Rule?

A

Orbitals are filled singly first, then doubly.

37
Q

Each energy level (n=1, n=2, etc.) is divided into…which have a fixed number of…

A

Each energy level is divided into sublevels spdf with a fixed number of orbitals

38
Q

What is a sublevel?

A

A group of orbitals w/ particular properties

39
Q

The s sublevel has what shape, how many orbitals, can hold how many e-?

A

Sphere, 1 orbital, 2 e- max

40
Q

The p sublevel has what shape, how many orbitals, can hold how many e-?

A

Dumbell, 3 orbitals, 6 e- max

41
Q

The d sublevel has how many orbitals, can hold how many e-?

A

5 orbitals, 10 e- max

42
Q

The f sublevel has how many orbitals, can hold how many e-?

A

7 orbitals, 14 e- max

43
Q

What is the formula for determining how many e- each energy level can hold?

A

2 x (n^2)

44
Q

What does electron arrangement refer to?

A

The number of e- per each main energy level

45
Q

Four things to consider when writing e- configurations:

A

1) determine total # of e-
2) Fill lowest energy sublevels first
3) 4s is filled before 3d and removed before 3d
4) Condensed e- configurations use the last noble gas as a placeholder

46
Q

What is the e- config for Copper Cu?

A

[Ar] 3d^5 4s^1

47
Q

What is the e- config for Chromium Cr?

A

[Ar] 3d^10 4s^1