Topic 10 - Organic Reactions Flashcards
What is a functional group?
A family of organic compounds that share certain characteristics.
What is a homologous series?
A βfamilyβ of organic compounds with the same functional group. They differ from each other by the number of atoms they posses but they maintain characteristics between different members of the family.
Give the word equation for the complete combustion of ethene (an alkene).
Ethene + Oxygen ββ> Carbon Dioxide + Water.
What is the name of the reaction where an alkene becomes an alkane? What reactant is used to change the alkene?
It is called hydrogenation since it uses hydrogen to remove the double bond in the alkene and reconfigure it to have more hydrogen atoms.
Give the word and symbol equation for the reaction between ethene and bromine.
Ethene + Bromine ββ> Dibromoethane.
C2H4 + Br2 ββ> C2H4Br2
What is the general formulae for alkenes?
C(n)H(2n)
What is the general formula for alkanes?
C(n)H(2n+2)
What is used to speed up the hydrogenation reaction?
A catalyst that isnβt used up.
Give the word and symbol equation for the reaction between ethene and steam. Is this reaction reversible?
Ethene + Steam ββ> Ethanol
C2H4 + H20 <ββ C2H5OH
This reaction is reversible.
What is the general formula for alcohols?
C(n)H(2n+1)OH
What is the general formula for carboxylic acids?
C(n)H(2n-1)OOH
Give the formula for ethanol.
C2H5OH.
Give the formula for Ethanoic Acid.
C2H3OOH or CH2CHOOH
Give the general formula for esters.
C(n)H(2n)OO
Give the word and symbol equation for alcoholic fermentation in yeast.
Glucose ββ> Ethanol + Carbon Dioxide
C6H12O6 ββ>2C2H5OH + 2CO2
Apart from alcoholic fermentation, how else is ethanol produced?
By reacting ethene (obtained by cracking fractions of crude oil) with steam in the presence of a catalyst.
Give the word and symbol equation for the complete combustion of ethanol.
Ethanol + Oxygen ββ> Carbon Dioxide + Water
C2H5OH + 3O2 ββ> 2CO2 + 3H2O
Give the word and symbol equation of Sodium reacting with ethanol.
Sodium + Ethanol ββ> Sodium Ethoxide + Hydrogen
2Na + 2C2H5OH ββ> 2C2H5ONa + H2
Give the word equation of the oxidation of ethanol.
Ethanol + Oxygen atoms from oxidising agent ββ> Ethanoic acid + Water.
Give the word equation for the reaction between Ethanoic acid and Sodium Carbonate.
Ethanoic acid + Sodium Carbonate ββ> Sodium Ethanoate + Water + Carbon Dioxide.
Why are carboxylic acids called βweakβ acids?
Carboxylic acids do not ionise 100% of their hydrogen molecules, unlike strong acids, hence they have a higher pH.
How do you make esters?
By reacting a carboxylic acid and an alcohol.
Give the word equation for the reaction between Ethanoic acid and Ethanol.
Ethanoic acid + Ethanol ββ> Ethyl ethanoate + Water.
This reaction is reversible.
What is the general word formula for a reaction between a carboxylic acid and an alcohol?
Carboxylic acid + Alcohol ββ> Acid + Water
When an alcohol and a carboxylic acid react to form an ester, what type of chemical is used as a catalyst?
A strong acid.
What type of reaction is producing ethanoic acid from ethanol?
Oxidation.
In regards to esters, what does it mean when we call them βvolatileβ?
That they evaporate easily or quickly and that they have a low boiling point.
What is the general formula for the reaction between a carboxylic acid and a carbonate? Use the example of ethanoic acid and calcium carbonate.
Ethanoic acid + Calcium carbonate β> Calcium Ethanoate + Carbon Dioxide + Water.
Name the 1. Reactant 2. Reaction conditions 3. Other products of the reaction that changes ethanoic acid into ethanol.
Reactant - Potassium Dichromate.
Reaction conditions - Hot + high pressure.
Other product - Water.
What is the reaction between ethene and bromine?
ethene + bromine β> dibromoethane
What is the reaction of pentene with hydrogen?
Pentene + hydrogen β> pentane (using a catalyst)
What is the reaction between ethene and steam?
Ethene + steam <β> ethanol (using a catalyst)
What are the first four carboxylic acid molecules?
Methanoic acid
Ethanoic acid
Propanoic acid
Butanoic acid
What do you do (chemically) to get from carboxylic acids to esters?
Replace the H atom in the COOH group by a hydrocarbon group like CH3
How is ethanol made?
By fermentation of sugars from plant material with yeast.
What three uses are there for ethanol?
As a perfume solvent
In alcoholic drinks
As a biofuel
What is the reaction for the combustion of ethanol?
Ethanol + oxygen β> carbon dioxide + water
What is the reaction of ethanol with sodium?
Sodium + ethanol β> Sodium ethoxide + hydrogen
What is the reaction for the oxidation of ethanol?
Ethanol + oxygen atoms from oxidising agent β> ethanoic acid + water
What is the reaction between ethanoic acid and sodium carbonate?
Ethanoic acid + sodium carbonate β> sodium ethanoate + water + carbon dioxide
What is the general reaction between carboxylic acid and alcohol?
Carboxylic acid + alcohol <β> ester + water using an acid catalyst
What are the characteristics of esters?
They have distinctive smells and are volatile