Topic 10 - Chemical Equilibrium Flashcards
1
Q
what is a reversible reaction?
A
- a reaction which can go in two directions.
- the reactants can react to form products and the products can react to form the original reactants.
2
Q
what is dynamic equilibrium?
A
- in a closed system
- when the rate of the forward reaction is equal to the rate of the reverse reaction.
- At dynamic equilibrium, concentration of the reactants and products remains constant.
- reaction has reached a position of equilibrium.
3
Q
what is a closed system?
A
it is a system where no chemicals/substances can move in or out of the apparatus.
4
Q
what can disturb position of equilibrium?
A
- change in pressure of a gaseous reaction
- changing concentration of reactants/products in an aqueous reaction
- change in temperature of the system.
5
Q
if temperature is increased in the system, what happens to the position of equilibrium?
A
- temperature increase shifts the position of equilibrium in the endothermic direction to lower the temperature.
6
Q
if pressure was increased, what happens to the position of equilibrium?
A
- position of equilibrium shifts to the side with less gas molecules to lower the pressure.
7
Q
If concentration of reactant/product was increased, what happens to the position of equilibrium?
A
- position of equilibrium shifts in the opposite direction to lower the concentration of the reactant/product.
8
Q
equilibrium constant Kc expression?
A
- Kc = products/reactants
- use square brackets.
- square each substance if there is more than one molecule
- include state symbols inside square brackets.
- to find units, replace substances in formula with units (moldm-3).
- treat like fraction and divide if needed.
- sometimes there are no units.