Topic 1 - Qualitative Analysis Flashcards

1
Q

Why is chemical analysis useful?

A

Blood tests can monitor general health, diagnose diseases, and check to see the alcohol content of someones blood. Water companies use it to check the purity of the drinking water by analysing for potentially dangerous chemicals.

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2
Q

What is qualitative analysis?

A

It tells you what substance is present. It is used to detect poisonous substances in things like drinking water.

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3
Q

What is quantitative analysis?

A

This tells you how much of a substance is present. It would be used in circumstances such as testing the amount of alcohol a driver has consumed.

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4
Q

How do you test for positive metal ions using flame tests?

A

Clean a nichrome wire by dipping in HCL then heating in a bunsen flame. Place the sample on the clean wire and place in a blue bunsen flame.

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5
Q

What colours are created in flame tests?

Na, K, Ca, Cu

A

Sodium (Na+) - Yellow

Potassium (K+) - Lilac

Calcium (Ca2+) - Brick red

Copper (Cu2+) - Blue/green

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6
Q

How do you test for positive metal ions using sodium hydroxide?

A

Dilute sodium hydroxide solution is added to a suspected ion. Colour of precipitate is noted.

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7
Q

What colours are the precipitates created?

Al, Ca, Cu, Fe2, Fe3

A

Aluminium (Al3+) - White precipitate, dissolves in excess NaOH

Calcium (Ca2+) - White precipitate

Copper (Cu2+) - light blue precipitate

Iron II (Fe2+) - Dark green ppt

Iron III (Fe3+) - Brown ppt

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8
Q

what is the ionic equation for aluminium reacting with sodium hydroxide?

A

Al3+(aq) + 3OH-(aq) -> Al(OH)3(s)

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9
Q

How do you test for acids (containg H+)

A

Blue litmus paper - goes red

Universal indicator - goes red, yellow, or orange depending on strenght of acid

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10
Q

How do you test for ammonium ions (NH4+)?

A

Add NaOH solution and warm. Test any gas given off with red litmus paper. It will turn blue

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11
Q

What is the ionic equation of ammonium reacting with sodium hydroxide

A

NH4+(aq) + OH-(aq) -> NH3(g) + H2O(l)

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12
Q

How do you test for carbonate ions (CO32-)?

A

Add dilute hydrochoric acid, then bubble the gas produced through limewater. Fizzing and a colourless gas that turns limewater cloudy.

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13
Q

what is the equation of a carbonate reacting with HCL

A

CO32-(aq) + 2H+(aq) -> H2O (l) + CO2(g)

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14
Q

How do you test for hydroxide ions (OH-) found in alkalis.

A

red litmus paper turns blue

universal indicator turns dark green, violet, or dark blue depending on the strength of the alkali.

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15
Q

How do you test for sulphate ions (SO42-)?

A

Add dilute hydrochloric acid, then a few drops of barium chloride solution (BaCl2). White ppt of barium sulphate is formed.

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16
Q

What is the ionic equation of HCL reacting with BaCl2 and sulphate ions?

A

Ba2+(aq) + SO42-(aq) -> BaSO4(s)

17
Q

How do you test for halide ions (chloride, bromide and iodide)

A

Add dilute nitric acid and silver nitrate solution and note the colour of precipitate.

Cl- - white

Br- - Cream

I- - Yellow

18
Q

What is the ionic equation of silver nitrate, nitric acid and chloride

A

Ag+(aq) + Cl-(aq) -> AgCl (s)