Topic 1 - Atomic Structure & the Periodic Table Flashcards

1
Q

What is the first ionisation energy definition?

A

The energy needed to remove one electron from each atom in 1 mole of gaseous atoms to form 1 mole of gaseous 1+ ions.

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2
Q

What is the second ionisation energy
definition?

A

The second ionisation energy is the energy needed to remove 1 electron from each ion in 1 mole of gaseous 1+ ions to form 1 mole of gaseous 2+ ions.

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3
Q

What is the relative atomic mass definition?

A

The weighted mean mass of an atom of an element relative to 1/12th of the mass of an atom of carbon-12 which has a mass of 12.

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4
Q

What is the definition of relative isotopic mass?

A

the mass of an atom of an isotope relative to 1/12th of the mass of an atom of carbon-12 which has a mass of 12.

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5
Q

What elements have exceptions to the usual rules of filling electron shell configurations?

A

Chromium and Copper - both fill 3d first

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6
Q

What is the Pauli Exclusion Principe?

A

Two electrons cannot occupy the same orbital unless they have opposite spins. Electron spin is usually shown by the use of upward + downward arrows.

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7
Q

What flame test colour does lithium go?

A

Red

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8
Q

What flame test colour does sodium go?

A

Yellow

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9
Q

What flame test colour does potassium go?

A

Lilac

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10
Q

What flame test colour does Calcium go?

A

Orange red

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11
Q

What flame test colour does barium go?

A

Green

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12
Q

What flame test colour does copper go?

A

Green blue

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13
Q

Why do the flame tests change colour? What causes this?

A

When electrons are promoted/jump from their ground state to a higher level, they also return to their ground state, which is when the visible light is emitted.

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14
Q

What three things affect the ionisation energy?

A

Atomic Radius
Nuclear Charge
Elctron Shielding

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15
Q

What happens to the first ionisation energies as you go down group one?

A

They decrease

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16
Q

What happens to first ionisation energies across periods?

A

They generally increase

17
Q

What are the exceptions to the first ionisation energies increasing across a period?

A

Slight drop between group 2 and 3 and groups 5 and 6.

18
Q

Are each successive ionisation energies greater or less than the last?

A

Greater

19
Q

Why do C and Si have high melting and boiling points?

A

-Giant covalent structures.
-require lots of energy to break.

20
Q

What happens to atomic radius across a period?

A

Generally decreases