Topic 1 - Atomic Structure and The Periodic Table Flashcards

1
Q

What charge do atoms have?

A

Neutral charge - they have the same number of protons and electrons. The equal but opposite charges will then cancel each other out

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2
Q

What is the nucleus of an atom? What is its charge?

A

The nucleus is the central part of the atom. It contains the protons and the neutrons and has a positive charge due to the protons and the neutral electrons. Almost the whole mass of the atom is concentrated in the nucleus

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3
Q

What is the approximate radius of an atom?

A

Atoms have a radius of about 0.1 nano-metres

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4
Q

What are some features of electrons? Where are electrons found on the atom?

A

Electrons orbit the nucleus in ‘shells’. They have a negative charge and have virtually no mass

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5
Q

What can we deduce from the nuclear symbol of an atom? How can we use it to find the number of neutrons in the atom

A

From the nuclear symbol of an atom, we can deduce its atomic (proton) number and its mass number. We can then subtract the proton number from the mass number to determine the number of neutrons in the atom

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6
Q

What are isotopes?

A

Isotopes are different forms of the same element which have the same number of protons and electrons but a different number of neutrons. Isotopes will therefore have different mass numbers

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7
Q

What is a compound?

A

Compounds are substances formed of two or more elements. The atoms in chemical compounds are each in fixed proportions and are held together through chemical bonds

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8
Q

What do compounds formed from metals and non-metals consist of?

A

Compounds formed of metals and non-metals consist of ions. The metal ions lose electrons to form positive ions whilst the non metal gains electrons to form negative ions. These opposite charges mean that the ions are strongly attracted to each other through ionic bonding

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9
Q

What do compounds formed from non-metals consist of?

A

Compounds formed from non-metals consist of molecules. Each atom shares an electron with another atom in a process known as covalent bonding

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10
Q

What is a mixture?

A

A mixture contains two or more substances that are not chemically bonded together

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11
Q

How are mixtures unlike compounds?

A
  • Substances in a mixture can be separated using physical methods such as filtration, freezing and distillation
  • Mixtures have varying compositions whereas compounds have a fixed, definite formula
  • In a mixture, substances keep their properties whilst this is not always the case in a compound
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12
Q

How do the properties of a mixture change relative to the properties of the individual substance?

A

Properties of a mixture are just mixtures of the properties of the individual parts. For example, a mixture of iron powder and sulphur powder will show the properties of both iron and sulphur. It will contain grey, magnetic pieces of iron and bright yellow pieces of sulphur

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13
Q

Name three techniques we can use to separate mixtures

A

Filtration, Crystallisation, Chromatography (Evaporation, Simple Distillation)

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14
Q

Describe the method to carry out Evaporation

A
  • Pour the solution into an evaporating dish
  • Slowly heat the solution (the solvent will evaporate and the solution will become concentrated - allowing for the formation of crystals)
  • We then keep heating the dish until there is no solvent left and only crystals remain
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15
Q

Describe the method to carry out crystallisation

A
  • Pour the solution into an evaporating dish and gently heat it. Some of the solvent will evaporate and the solution will become more concentrated
  • Once some of the solvent has evaporated, remove the solution from the heat and allow it to cool
  • The salt should then begin to form crystals as it becomes insoluble in the cold, highly concentrated solution
  • We then filter the crystals out of the solution and leave them in a warm place to dry
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16
Q

Describe a method that could be used to separate rock salt

A

We could use a process of filtration and crystallisation to separate rock salt;

  • Grind the mixture so that the salt crystals are small and will dissolve easily
  • Put the mixture in the water and stir. The salt is soluble and therefore will dissolve whilst the sand is insoluble and does not dissolve
  • Filter the mixture, the grains of sand wont fit through the pores of the filter paper therefore they will be collected whilst the salt passes through
  • We then evaporate the water to obtain salt crystals in a dish
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17
Q

When could we use a process of filtration?

A
  • Filtration could be used to separate an insoluble solid from a liquid reaction mixture
  • We could also use filtration during a purification process as solid impurities could be filtered out through filtration
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18
Q

Through what process could we separate different dyes in an ink?

A

Paper chromatography

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19
Q

Why do we use a pencil to draw a line at the bottom of the chromatography paper?

A

We use a pencil line as if we were to use pen ink, it would be dissolve in the solvent. Pencil however is insoluble

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20
Q

What was John Dalton’s theory of the atom?

A

At the start of the 19th century, John Dalton described atoms as solid spheres and said that different spheres made up the different elements

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21
Q

What was JJ Thompson’s theory of the atom?

A

JJ Thompson was able to conclude from his experiments that an atom had to contain even smaller, negatively charged particles. The ‘plum pudding’ model of the atom was developed showing the atom as a ball of positive charge with electrons stuck in it

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22
Q

Through what experiment did Rutherford disprove the ‘plum pudding’ model of the atom?

A

Alpha particle scattering experiment

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23
Q

Describe how Rutherford carried out his experiment. What did they find?

A
  • Positively charged alpha particles were fired at a thin sheet of gold
  • They found that though most of the particles passed straight through the gold sheet, some were deflected more than expected and a small number even were deflected backwards
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24
Q

What did Rutherford’s experiment show?

A

From the experiment, Rutherford was able to display the nuclear model of the atom. In this, most of the mass is concentrated in the nucleus at the centre of the atom. A ‘cloud’ of negatively charged electrons then orbits this nucleus - therefore most of the atom is merely empty space. When alpha particles came near the positive charge of the nucleus, they were deflected. However, because most of the atom is empty space, most of the alpha particles passed straight through

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25
Q

What was Niels Bohr’s model of the atom?

A

Bohr proposed that electrons ‘orbit’ the nucleus in fixed shells and are not anywhere in between. Each shell is then a fixed distance from the nucleus

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26
Q

Who proved the existence of the neutron?

A

James Chadwick proved the existence of neutrons, resulting in a model of the atom which is used today

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27
Q

What process would we use to separate a mixture of liquids?

A

Fractional distillation

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28
Q

What could be a disadvantage of fractional distillation?

A

Liquids with similar boiling points could be difficult to separate out individually

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29
Q

What is another term for electron shells ?

A

Energy Levels

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30
Q

Who developed the ‘Table of Elements’ ? When was this developed ? How was it devised?

A

Dimitri Mendeleev developed the ‘Table of Elements’ in 1869. The table was based on arranging the atoms mainly by Relative Atomic Mass but whilst also leaving gaps for elements that had not been discovered yet

31
Q

What discovery confirmed that Mendeleev was correct in not placing atoms in strict order of atomic mass and instead taking into accounts their properties also?

A

The discovery of isotopes - isotopes have different atomic masses but the same chemical properties, confirming that Mendeleev was correct in also taking properties into account

32
Q

How were elements classified in the early 1800s ?

A

In the early 1800s, elements were classified based on;

  • Physical and Chemical properties
  • Relative atomic masses
33
Q

How are elements classified today?

A

Today, elements are classified based on atomic (proton) number

34
Q

Describe two changes that Mendeleev made to the early periodic tables

A
  • Gaps were left for elements that were yet to be discovered
  • Although most of Mendeleev’s elements were in order of relative atomic mass, this was switched if physical properties meant it changed
35
Q

What are the Group 1 elements known as?

A

The alkali metals

36
Q

What are the trends for the alkali metals as you go down the group?

A
  • They are increasingly reactive - the valence electron is more easily lost as the attraction between the nucleus and the valence electron decreases due to greater shell shielding
  • Lower melting and boiling points
  • Higher relative atomic mass
37
Q

What ions do Group 1 atoms form?

A

Group 1 atoms form 1+ ions - this requires little energy for them to obtain a full valence shell

38
Q

What is the reaction of Group 1 metals with water?

A

When Group 1 metals react with water, they react vigorously to produce hydrogen gas and metal hydroxides - salts that dissolve in water to produce alkaline solutions

39
Q

What is the reaction of Group 1 metals with chlorine?

A

Group 1 metals react vigorously when heated in chlorine to form white metal chloride salts

40
Q

What is the reaction of Group 1 metals with oxygen?

A

Group 1 metals react with oxygen to form a metal oxide. Different oxides will form depending on the Group 1 metal that the oxygen is reacted with e.g. potassium reacts to form a mixture of potassium peroxide and potassium super-oxide

41
Q

What are the Group 7 elements known as?

A

Group 7 elements are known as the Halogens

42
Q

What are the trends as we go down Group 7?

A
  • The halogens become less reactive - it is harder to gain an extra electron as there is more shell shielding and therefore less attractive force from the nucleus
  • The halogens have increasing melting and boiling points
  • The halogens will also have higher relative atomic masses
43
Q

What sorts of compounds will halogens form? (with non-metals)

A

Halogens will form covalent compounds with non-metals so that they can achieve a full valence shell. They will therefore form covalent compounds with non-metals

44
Q

Can halogens produce a displacement reaction?

A

Yes, displacement reactions can occur between a more reactive halogen and the salt of a less reactive one. For example, bromine could displace iodine due to the trend in reactivity

45
Q

What are the Group 0 (8) elements called?

A

The Group 0 or Group 8 elements are known as noble gases

46
Q

What form are halogens found in?

A

Halogens are found in the form of as molecules - existing as pairs of atoms (e.g. I2 iodine)

47
Q

How many electrons do the Group 0 elements have in their valence shell?

A

Group 0 elements have eight electrons in their outer shell, except for helium which has two. However, this means that they all have a full valence shell

48
Q

In what state do noble gases exist?

A

Noble gases exist as monatomic gases - single atoms that are not bonded to each other

49
Q

Describe the flammability of noble gases

A

Noble gases are inert and therefore they are not flammable

50
Q

Describe the patterns of the elements as you go down Group 0

A
  • As you go down the group, the boiling points of the gases increase along with relative atomic mass. This is because an increased number of electrons in each atom creates greater inter-molecular forces between them which need to be overcome
51
Q

Structural formula

A

the minimal detail that shows the arrangement of atoms in a molecule. Structural formula shows the atoms and the bonds in between them

52
Q

Displayed formula

A

spatial arrangement of atoms in a compound and the atoms of elements that are bonded together. similar to structural but the way the atoms are arranged are shown.

53
Q

skeletal formula

A

simplified organic formula shown by removing the hydrogens and carbon. carbon backbone. functional groups are displayed.

54
Q

Alkyl

A

a functional group containing only carbon and hydrogen Cn+H2n+1 e.g. methyl:CH3, Butyl C2H5

55
Q

Aliphatic

A

A compound containing carbon and hydrogen joined together in straight chains, branched chains and non aromatic rings

56
Q

Alicyclic

A

an aliphatic compound arranged in non-aromatic rings with or without side chains

57
Q

Aromatic

A

Contains a Benzene ring

58
Q

Saturated bond

A

a carbon single-single bond

59
Q

Unsaturated

A

the presence og multiple carbon-carbon bonds such as c=c or C triple bond C

60
Q

Structural Isomer

A

compounds with the same molecular formula but different structural formula

61
Q

Isotopes

A

atoms of the same element with different numbers of neutrons and different masses

62
Q

atomic structure

A

must be described in terms of protons, neutrons, electrons, atoms, ions. use the atomic number the mass number and ionic charge

63
Q

Relative isotopic mass

A

mass compared with 1/12th mass of carbon 12.

64
Q

Relative atomic mass

A

weighted mean mass compared to 1/12th mass compared with carbon 12.

65
Q

Mass spectrometry

A

measures the mass to charge ratio of ions. plot of intensity as a function of the mass to charge ratio

66
Q

CO3(2-) [H2CO3]

A

carbonate ion [carbonic acid]

67
Q

NO3- [H2NO3-]

A

nitrate ion [nitric acid]

68
Q

atomic orbitals

A

a region around the nucleus that can hold up to two electrons with opposite spin

69
Q

shape of S orbital

A

Sphere (drawn as x y z axis)

70
Q

shape of P orbital

A

Dumbbell shape

71
Q

empirical formula

A

the simplest whole number ratio of atoms of each element in a compound

72
Q

anhydrous

A

lack of water, water has been removed

73
Q

hydrated

A

water containing

74
Q

water of crystallisation

A

water incorporated into the crystalline framework of metal complex or salt.