Tooth coloured materials 1 Flashcards
how are fillers classified?
by material, shape and size
what shape are fillers?
irregular or spherical
why are spherical particles easier
easier to incorporate into a resin mix and to fill more space leaving less resin.
why do we add different size spherical fillers
One size spherical particle occupies a certain space.
Adding smaller particles fills the space between the larger particles to take up more space.
what does inorganic filler reduce
- polymerisation shrinkage
- water sorption
- thermal expansion
what does inorganic filler increase:
- compressive/ tensile strength
- modulus of elasticity
- abrasion resistance
what is the general role of the coupling agent
creates a chemical bond
between filler particle and resin matrix
transfers stresses
give eg of coupling agent
organisilane (bifunctional molecule)
how does organisilane work
siloxane end bonds to hydroxyl groups on filler
methacrylate end polymerizes with resin
why are coupling agents used
-improves adherence of resin to filler surfaces
- chemically coat filler surfaces and increase strength
what are disadvantages of silane
age quickly in a bottle and becomes ineffective
what are silanes sensitive to
water so the silane filler bond breaks down with moisture.
Water absorbed into composites results in hydrolysis of the silane bond and eventual filler loss.
eg of common silane agents
vinyl triethoxysilane
methacryloxypropyltrimethyloxysilane(MOPS)
what are flowable composites resins
- percentage filler content by weight (50% to 70%) less than that of traditional hybrid composite resins= give lower viscosity
why are flowables bad?
- they have lower filler volumes so they give increased shrinkage
and wear with decreased strength
what are packable composites
- AKA bulk placed composite
- stiffer material
- can be packed in like amalgam
what particle type do packable composites have
- larger filler particles or even fibres to improve packing qualities
why are packable composites more difficult to sculpt and voids are more common
because they have higher viscosities
why do we need bonding agents to enamel
composites are hydrophobic
but bonding to enamel is easy as its 95% mineral HAP essentially a ceramic
what is etch made up of
an acid 30-40% phosphoric acid