TOF mass spectrometry Flashcards

1
Q

isotopes are…

A

atoms of the same element (same number of protons) with a different number of neutrons

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2
Q

ionisation chamber

A

a high-speed electron is fired at the atom, which knocks an electron off (forming a positive ion) and causes a knock on effect

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3
Q

acceleration

A

the isotopes are all accelerated to the same speed (same kinetic energy)

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4
Q

ion drift

A

the ions travel through the chamber, and separate based on mass over time (heavier electrons travel more slowly)

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5
Q

deionisation

A

the ions hit a negatively charged plate. they remove electrons as they do so, which causes a movement of electrons within the plate and therefore a current

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6
Q

mass spectrum

A

the charges caused by each isotope are used to calculate relative abundance. this is graphed

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7
Q

kinetic energy equation

A

Ek = 0.5 x mass x velocity^2

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8
Q

as mass increases, velocity…

A

decreases

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