Titrations Flashcards
What is used for any acid base titration
An indicator must be used that will help determine when the titration is at its end point
What are indicators
A special chemical that change colour when at a different Ph
Give an example of a indicator that can be used in titration
For example phenolphthalein is an indicator that is colourless in a low acidic pH but bright pink on a high alkaline pH
What can a titration curve show
The rapid change in the mixture
What is the centre of the vertical section of the curve called
Equivalence point of the titration and it is this part that yeh indicator is trying to indicate
Why is the choice of an indicator important
It must change colour at a pH that is in the vertical part of the curve otherwise it will miss the equivalent point rending that titration pointless
What is the equivalent point
The point in a titration where the volume of k e solution exactly matches the volume of the other solution
What does the indicator depend on
On the strengths of the acid and base that are reacting.Different indicators will change colours at different pH. Therefore the pH of the acid and the base must be considered.
What are the two factors in conducting a titration curve
The pH
Base
What would the indicator phenolphthalein
So it would be suitable for a strong acid/strong base titration but would not above the vertical section of the curve
Enthalpy Changes
All chemical reactions can be classified into two distinct types exothermic or endothermic. The category the reaction falls under is determined by enthanlpy change that takes place during the reaction
Define Enthalpy
The heat content stored in a chemical system and
Describe endothermic reaction
Energy in the form of heat is taken in by the chemical system in order to break the bonds in the reactants, and energy is given out when new bonds from the products.
If more energy is needed to break the bonds than is released when bonds are made then the reaction is endothermic
Explain exothermic
If the reverse is the case and more energy is released when bonds are made than taken in when bonds are broken, then the reaction is exothermic
What does enthalpy
Heat energy
What is an empathy change
It is about energy being given out by a reaction(exothermic) or taken in by a reaction (endothermic)
What is the activation energy
Energy needed to start a reaction
Define standard enthalpy
The enthalpy change that occurs when one mole of a compound form from its elements under standard conditions
Define standard enthalpy change of combustion
The enthalpy change that occurs when one mole of a compound completely combusts oxygen under standard conditions
Define enthalpy change of neutralisation
The enthalpy change that occurs when an acid is neutralised by a base forming one mole of water under standard conditions
Define enthalpy change of reaction
The enthalpy change that occurs in the molar quantities expressed in the equation understand condition
Define standard conditions
25C/298k, 100kPa/1 atm pressure ,1 moldm3 solution concentration
Define standard enthalpy change equation
Equation can be written that shows theses different enthalpy change and their specific definition
Endothermic reactions
Energy profile shows that the products have more enthalpy than the reactants
heat is taken in from the surroundings so the enthalpy of the system increases
this shows a decrease in temperature
the reaction is not over until the system is back to the same temperature as the surroundings- all the necessary heat energy has been taken in