Titrations Flashcards

1
Q

What is used for any acid base titration

A

An indicator must be used that will help determine when the titration is at its end point

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2
Q

What are indicators

A

A special chemical that change colour when at a different Ph

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3
Q

Give an example of a indicator that can be used in titration

A

For example phenolphthalein is an indicator that is colourless in a low acidic pH but bright pink on a high alkaline pH

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4
Q

What can a titration curve show

A

The rapid change in the mixture

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5
Q

What is the centre of the vertical section of the curve called

A

Equivalence point of the titration and it is this part that yeh indicator is trying to indicate

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6
Q

Why is the choice of an indicator important

A

It must change colour at a pH that is in the vertical part of the curve otherwise it will miss the equivalent point rending that titration pointless

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7
Q

What is the equivalent point

A

The point in a titration where the volume of k e solution exactly matches the volume of the other solution

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8
Q

What does the indicator depend on

A

On the strengths of the acid and base that are reacting.Different indicators will change colours at different pH. Therefore the pH of the acid and the base must be considered.

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9
Q

What are the two factors in conducting a titration curve

A

The pH

Base

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10
Q

What would the indicator phenolphthalein

A

So it would be suitable for a strong acid/strong base titration but would not above the vertical section of the curve

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11
Q

Enthalpy Changes

A

All chemical reactions can be classified into two distinct types exothermic or endothermic. The category the reaction falls under is determined by enthanlpy change that takes place during the reaction

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12
Q

Define Enthalpy

A

The heat content stored in a chemical system and

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13
Q

Describe endothermic reaction

A

Energy in the form of heat is taken in by the chemical system in order to break the bonds in the reactants, and energy is given out when new bonds from the products.
If more energy is needed to break the bonds than is released when bonds are made then the reaction is endothermic

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14
Q

Explain exothermic

A

If the reverse is the case and more energy is released when bonds are made than taken in when bonds are broken, then the reaction is exothermic

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15
Q

What does enthalpy

A

Heat energy

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16
Q

What is an empathy change

A

It is about energy being given out by a reaction(exothermic) or taken in by a reaction (endothermic)

17
Q

What is the activation energy

A

Energy needed to start a reaction

18
Q

Define standard enthalpy

A

The enthalpy change that occurs when one mole of a compound form from its elements under standard conditions

19
Q

Define standard enthalpy change of combustion

A

The enthalpy change that occurs when one mole of a compound completely combusts oxygen under standard conditions

20
Q

Define enthalpy change of neutralisation

A

The enthalpy change that occurs when an acid is neutralised by a base forming one mole of water under standard conditions

21
Q

Define enthalpy change of reaction

A

The enthalpy change that occurs in the molar quantities expressed in the equation understand condition

22
Q

Define standard conditions

A

25C/298k, 100kPa/1 atm pressure ,1 moldm3 solution concentration

23
Q

Define standard enthalpy change equation

A

Equation can be written that shows theses different enthalpy change and their specific definition

24
Q

Endothermic reactions

A

Energy profile shows that the products have more enthalpy than the reactants
heat is taken in from the surroundings so the enthalpy of the system increases
this shows a decrease in temperature
the reaction is not over until the system is back to the same temperature as the surroundings- all the necessary heat energy has been taken in

25
Q

what is an example of endothermic reaction

A

photosynthesis

26
Q

exothermic reaction

A

The energy profile shows that the products have less enthalpy than the reactant
Heat energy has been transferred from the chemical system to the surroundings as the enthalpy of the system decreases
this shows that the temperature decrease
the reaction is not over until the system is back to the same temperature as the surroundings- all the heat energy has dissipated into the surrounding-all the heat energy has dissipated into the surroundings

27
Q

what an example of exothermic reactions

A

combustion

respiration

28
Q

how can we measure enthalpy change

A

temperature is measured using a thermometer
heat is a measure of the total energy of all the particles present in a substance- the number of particles matter
a bath of warm water will have more heat than a red hot nail because there are so many more particles in it
heat always flows from high to a low temperature

29
Q

Thermochemistry

A

most chemical reactions involve an energy change:
the overall change will result in either :
more energy being put in to the reaction to break bonds than is given out (endothermic)
more energy being produced by forming bonds that is used to break the bonds(exothermic)