Titanium Alloys Flashcards
What rank is titanium in the most abundant elements on the earths crust?
4th
What kind of layer does titanium naturally form?
A stable adherant oxide film.
What are the three reasons titanium is compatible with carbon fibre reinforced polymers?
1-titanium and graphite have similar linear thermal expansion coefficients
2-Both at cathodic end of electrochemical scale, this avoids galvanic corrosion.
3-Similar youngs modulus to unidirectional carbon fibre which eases residual stresses.
Thermomechanical processing accounts for what percentage of the cost for titanium?
50%
Describe the Kroll Process.
Titanium Ore (Rutile) is combined with Chlorine and Coke to produce Titanium tatrachloride (Tickle). Tickle is then added to magnesium to produce Titanium sponge and Magnesium Chloride. The sponge is then added to alloying elements and Ti scrap before being formed into compacts and welded together into an electrode. The electrode is then vaccum arc melted to form ingots. It can then be hot forged to break its core structure.
What is the modern FFC “Metalisis” Process?
A disruptive process from cambridge that mixes Titanium Oxide with and additional metal Oxide. Its then blended, pressed and sintered into a cathode where the electrochemical process occurs. Here oxygen elements react with the anode leaving a pureish metal cathode.
What are the benefits of the FFC process?
- Very homogenous output
- Small grain size that would take mass hot forging to produce after the Kroll process.
- Can produce some alloys the Kroll process cant (Tungsten)
What are the names of new processes that can form Titanium powder straight from ore?
Armstrong Process
MER Process
The metallurgy of titanium changes at a transus temperature. What is this property called?
Allotropic
What is Titaniums transus temp?
883 celsius
What are the two titanium crystal structures?
Alpha HCP phase
Beta BCC phase
What do stabalising elements do?
Change the transus temperature.
State some Alpha stabalisers.
Aluminium, Oxygen
State some Beta stabalisers.
Vanadium, Molybdinum, Niobium, Iron, Silicon
What affect does a small addition (<0.5wt%) interstitials have on Titanium?
Massively increases strength but at the same time drastically reduces elongation to failure.