Titanium Flashcards
What are the sectors that use titanium?
Commercial aerospace
military aerospace
Power generation
CPI and Desalination
What are the advantages of titanium?
Low density
Excellent corrosion resistance
High melting point
High specific strength
Compatible with CFRP
Excellent properties at high temperatures
What are the disadvantages of Titanium
Expensive to machine
Low wear resistance
Difficult to form
Pick up of oxygen + nitrogen ^ 500*C
Expensive £25k/tonne
lots of work to remove oxygen
Why is titanium with CFRP?
Similar linear expansion coefficient
Similar electrochemical potential
Can join easily - no galvonic corrosion
Similar youngs modulus (stifnnes)
What is the order of the FFC cambridge process?
- Tio2 and MeOx
- Blend
- Press
- Sinter
- Electrochemical process
In FFC what are the components of the electrochemical process
Anode - Graphite
Cathode - TiO2/MeOx
Crucible - Titanium
Liquid - molten CaCl2 800-1100*C
What process is used for the extraction of titanium?
Kroll Process
What are the components of the Kroll process?
- Rutile + Chlorine + Coke
- Magnesium and TIckle
- MgCl2 off product
- Alloys and scrap added to sponge
- Electrode
- Melt process
What is the general processing of titanium sponge?
- Titanium sponge
- Compaction
- Manufacture electrodes
- VAR (vacuum arc remelting)
- Ingots
- Breakdown Forging
- Blooms
What are some Alpha-Stabilising elements?
Aluminium
Oxygen
Nitrogen
What are the Beta-Stabilising elements?
Molybdenum
Iron
Vanadium
Chromium
Manganese
What does increasing Alpha stabilisers do?
Promotes alpha Phase
How can you promote the beta phase
Increase the quantity of beta stabilisers
What are the properties of Alpha dominant structures?
Higher Creep strength
Improved weldability
What are the properties of beta dominant structures?
Higher density
Increased heat treatment response
Higher short term strength
Increased strain rate sensitivity
Improved fabricability
What is meant by the beta transus?
The temperature at which titanium alloy transforms from alpha to beta form
What temperature is the beta transus
883*C
What is the structure of the atoms before and after beta transus
before - BBC
after - HCP
What is the effect of increasing interstitial elements on the properties of titanium?
Increases the tensile strength
Decreases the weld joint bend elongation
What is the order of interstitial elements in terms of effect on properties?
N > O > C
How can Alpha alloys be strengthened?
- Solution Strengthening from OXYGEN
- Grain Refinement (Hall Petch)
3.Cold work
What phase are non-heat treatable products?
Alpha
composition is such that beta cannot be retained at room temp in any form.
Always alpha
Martensite formed
What are the applications of alpha alloys?
CLadding in chemical plants
Hydraulic piping
Cooling towers
What are the benefits of Alpha Alloys
Highly corrosion resistant
Low maintanence cost