Third Law of Thermodynamics Flashcards

1
Q

What is the third law of thermodynamics?

A

The entropy of all perfect crystalline substances at T = 0 is 0

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2
Q

What is a microstate?

A

Energy state

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3
Q

Equation for Helmholtz

A

A = U - TS

if A = negative then it is spontaneous

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4
Q

Equation for Gibbs Free Energy

A

G = H - TS

If G = negative then it is spontaneous

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5
Q

For any process what is A and G?

A

delta A at constant T,V is greater than or equal to 0

delta G at constant T,P is greater than or equal to 0

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6
Q

Thermodynamic Square

A

V A T
U G S -> T & P -> V
S H P

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