Thermodynamics I, II (equations) Flashcards
ideal gas law/ what the constants are.
PV=nRT
n= number of mol.
R= 8.31
ATM to Pa
1 ATM = 1.013 x 10^5
Celsius to K
0 c= 273 k
Expansion Equations (3)
ΔL= α LΔT
ΔA= γAΔT
ΔV= βVΔT
Power
P= ΣE/T =F/A
Work
Fy=PAy
first law of thermodynamics
ΔU=Q+W
equations for isochoric process
Δv=0
Δw=0
ΔQ=ΔU
isobaric process equatiosn
ΔU=Q+PΔV= Q+W
isothermal process equations
Δu=0
Ti=Tf
What ΔU can equal
3/2nRt (monatomic)
5/2nRt (diatomic)
average kinetic energy
1/2mv^2=3/2kbT=1/3NmVrms^2
Vrms
root 3kbT/m= root 3RT/M
ideal monatomic gasses
u=3/2 nRT = N(1/2mvrms^2)=3/2NkbT
ideal diatomic gasses
5/2 nRT
u=k trans+ k rot
= 5/2nRT
phase changes
solid+liquid: Q=mHf
gas+liquid: Q=mHv
phase equations
solid: Q=mCΔT
liquid: Q=mcΔT
Gas: Q=mCΔT
efficiency
regular: e= W/Qh = Qh-Qc/Qh= 1-Qc/Qh
ideal: Qh=W
entropy
ΔS=ΔQ/T
rate of thermal expansion
Q/t=kA(th-tc/L)