Thermodynamics & Heat Transfer Flashcards
Thermo: Properties of Substances - Phases of a Pure Substance
Ideal gas law (formula)
pV = nRT
Thermo: Properties of Substances - Phases of a Pure Substance
What is a p-v-T diagram?
3D surface that predicts a substance’s phase based on the properties of presure, specific volume, and temp.
Thermo: Properties of Substances - Phases of a Pure Substance
What is the vapor dome?
The bell-shaped diving line at the liquid-vapor region.
Thermo: Properties of Substances - Phases of a Pure Substance
What other diagrams can be derived from a p-v-T diagram?
Pressur-Volume Phase Diagram (2D projection of the 3D p-v-T diagram, where one property is held constant. In this case, that is temperature.)
Vapor Dome Diagram
These are phase diagrams or equiplibrium diagrams.
Thermo: Properties of Substances - Phases of a Pure Substance
Define the saturated liquid line?
Left-hand part of the vapor dome curve that separates the liquid phase from the liquid-vapor phase.
Thermo: Properties of Substances - Phases of a Pure Substance
Define saturated vapor line?
Right-hand part of the vapor dome curve that separates the liquid-vapor phase from the vapor phase.
Thermo: Properties of Substances - Phases of a Pure Substance
Define isobars?
Lines of constant pressure.
Thermo: Properties of Substances - Phases of a Pure Substance
Above the vapor dome, the phase is what?
Gas
Thermo: Properties of Substances - Phases of a Pure Substance
What is the critical isobar?
The dividing line between liquid and gas that intersects the topmost part of the vapor dome**.
Thermo: Properties of Substances - Phases of a Pure Substance
What is the critical point?
The highest point of the vapor dome.
Thermo: Properties of Substances - Phases of a Pure Substance
What is the triple point?
A unique state at which solid, liquid, and gaseous phases can coexist.
Thermo: Properties of Substances - Phases of a Pure Substance
Define isotherms?
The lines of constant temperature.
Thermo: Properties of Substances - Phases of a Pure Substance
‘1. A substance is a subcooled liquid if:
its temperature is less than the saturation temperature corresponding to its pressure.
Thermo: Properties of Substances - Phases of a Pure Substance
‘2. A substance is in the liquid-vapor region if:
its temperature is equal to the saturation temperature corresponding to its pressure.
Thermo: Properties of Substances - Phases of a Pure Substance
‘3. A substance is a superheated vapor if:
its temperature is greater than the saturation temperature corresponding to its pressure.
Thermo: Properties of Substances - Phases of a Pure Substance
‘4. A substance is a subcooled liquid if:
its pressure is greater than the saturation pressure corresoponding to its temperature.
Thermo: Properties of Substances - Phases of a Pure Substance
‘5. A substance is in the liquid-vapor region if:
its pressure is equal to the saturation pressure corresponding to its temperature.
Thermo: Properties of Substances - Phases of a Pure Substance
‘6. A substance is a superheated vapor if:
its pressure is less than the saturation pressure corresponding to its temperature.
Thermo: Properties of Substances - State Functions (Properties)
Define intensive properties?
Properties that are independent of the amount of a substance present.
Thermo: Properties of Substances - State Functions (Properties)
Define extensive properties?
Properties that are dependent of the amount of a substance present.
Thermo: Properties of Substances - State Functions (Properties)
Examples of intensive properties:
temperature, pressure, stress
Thermo: Properties of Substances - State Functions (Properties)
Examples of extensive properties:
volume, strain, charge, mass
Thermo: Properties of Substances - State Functions (Properties)
Rankine scale (formula)
Tf + 459.67 degrees
Thermo: Properties of Substances - State Functions (Properties)
Kelvin scale (formula)
Tc + 273.15 degrees
Thermo: Properties of Substances - State Functions (Properties)
Define enthalpy?
Represents the total useful energy of a substance.
Thermo: Properties of Substances - State Functions (Properties)
Define entropy?
A measure of the energy that is no longer available to perform useful work within the current environment.
Thermo: Properties of Substances - State Functions (Properties)
Formula for heat energy (Q)?
Q = mcΔT
Thermo: Properties of Substances - State Functions (Properties)
Formula for quality (x)?
x = Mvapor / Mvapor + Mliquid
Thermo: Properties of Substances - Ideal Gases
Another ideal gas relationship for pressure, volume, and temperature? (formula)
p1V1 / T1 = p2V2 / T2
Thermo: Properties of Substances - Ideal Gases
How can you calculate the number of moles (n) of a substance?
(explanation and formula)
Using the mass (m) and molecular weight (MW).
n = m / MW
Thermo: Properties of Substances - Ideal Gases
Define isentropic processes.
entropy is constant
Thermo: Properties of Substances - Speed of Sound & Mach
What is a Mach number? (definition)
The ratio of an object’s speed to the speed of sound in the medium through which the object is traveling.