Thermodynamics Final Flashcards

1
Q

System

A

A quantity of matter or a region in space chosen for study

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2
Q

Surroundings

A

The mass or region outside the system

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3
Q

Boundary

A

The real or imaginary surface that separates the system from its surroundings. Can be fixed or movable.

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4
Q

Closed System (Control Mass)

A

A fixed amount of mass, and no mass can cross its boundary. Energy in the form of heat or work can cross. Volume doesn’t have to be fixed.

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5
Q

Open System (Control Volume)

A

A properly selected region in space, both mass and energy can cross its boundary. Fixed volume.

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6
Q

Control Surface

A

The boundaries of a control volume. It can be real or imaginary.

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7
Q

Property

A

Any characteristics of a system such as P, T, V, and m.

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8
Q

Intensive Properties

A

Those that are independent of the mass of a system, such as pressure, temperature, and density.

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9
Q

Extensive Properties

A

Those whose values depend on the size - or extent - of the system.

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10
Q

Specific Properties

A

Extensive properties per unit mass

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11
Q

Specific Gravity

A

The ratio of the density of a substance to the density of some standard substance at a specified temperature (usually water at 4 degrees C) NO UNIT

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12
Q

Specific Weight

A

The weight of a unit volume of a substance, HAS UNITS

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13
Q

Equilibrium

A

A state of balance

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14
Q

Thermal equilibrium

A

Same temperature throughout the entire system

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15
Q

Mechanical Equilibrium

A

No change in pressure at any point of the system with time

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16
Q

Phase Equilibrium

A

When the mass of each phase reaches an equilibrium level and stays there

17
Q

Chemical Equilibrium

A

No chemical reactions occur

18
Q

State Postulate

A

The state of a simple compressible system is completely specified by two independent, intensive properties.

19
Q

Process

A

Any change that a system undergoes from one equilibrium state to another

20
Q

Path

A

The series of states through which a system passes during a process

21
Q

Cv

A

Specific heat at constant volume

22
Q

Cp

A

Specific heat at constant pressure

23
Q

Kelvin Planck

A

It is impossible for any device that operates on a cycle to receive heat from a single reservoir and produce a net amount of work

24
Q

Clausius

A

It is impossible to construct a device that operates in a cycle and produces no effect other than the transfer of heat from a lower temperature body to a higher temperature body. A refrigerator cannot operate unless its compressor is driven by an external power source, such as an electric motor.