Thermodynamics definitions Flashcards

1
Q

Reversible process

A

For fluid undergoing reversible process, both the fluid and the surroundings can always be returned to their original states

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2
Q

Isentropic efficiency

A

For identical start and end pressures, a ratio of reversible power to real world power. A measure of how much a steady flow process approximates to an isentropic process.

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3
Q

Adiabatic

A

No heat transfer between the fluid and its surroundings.

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4
Q

Cycle

A

A series of processes which returns a system to it initial state

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5
Q

Reservoir

A

Thermodynamic system with a heat capacity large enough that can supply or absorb a finite amount of heat and remain at constant temperature

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6
Q

Source

A

System which supplies heat

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7
Q

Sink

A

System which accepts heat

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8
Q

Isentropic

A

A process in which there is no friction and no heat transfer. Also means constant entropy

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9
Q

Entropy

A

A thermodynamic property representing the unavailability of a system’s thermal energy for conversion into mechanical work. Measures degree of disorder in the system.

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10
Q

Closed system

A

Space containing fluid with boundary between the fluid and its surroundings

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11
Q

Property

A

Numerical values which define the system. Independent of the path taken to reach its state.

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12
Q

State postulate

A

‘simple’ equilibrium whose state can be determined by 2 independent properties

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13
Q

Gauge pressure

A

Pressure referenced to atmospheric pressure

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14
Q

Absolute pressure

A

Pressure referenced to vacuum at p=0

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15
Q

2-point temp scale

A

Defined by properties of a thermometric substance. T=0 at melting point

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16
Q

Thermodynamic temp scale

A

Not dependent on properties of a substance. Absolute zero when k=0

17
Q

Zeroth law

A

Two objects at the same temperature are at thermal equilibrium

18
Q

Process

A

Transforms system from 1 equilibrium state to another

19
Q

Path

A

Transition between start and end of a process

20
Q

Equilibrium

A

Net force = 0 when multiple forces are acting on an object

21
Q

Quasi-equilibrium

A

System always remains close to equilibrium as it moves from its start to end point of process.

22
Q

Work

A

force x distance through which the force acts

23
Q

Stationary system

A

Any change in ke/pe of system is small

24
Q

Internal energy

A

Summation of all the microscopic energies in a substance. Is a property

25
1st law thermodynamics
When any closed system is taken through a cycle, the net work done by the system upon the surroundings is equal to the net heat supplied to the system from the surroundings.
26
Independent property
Properties which can be combined
27
Extensive properties
Properties which depend on system size
28
Specific heat capacity
Quantity of energy required to raise the temperature of one unit mass by one degree.
29
Enthalpy
A combination property. It's the sum of internal energy and a term with the sense of work, pv. H = U + PV.
30
Isochoric
Constant volume
31
Isobaric
Constant pressure
32
Isothermal
No heat transfer
33
Flow work
Work to deform part of a boundary displacing volume V at pressure P.
34
Open system
Fluid continuously passes into and away from a system
35
Steady flow rate
Constant mass flow rate
36
Axiom
Something which can't be disproved, but clearly no case exists which disproves it
37
Isolated system
No heat, work or mass crosses the system boundary
38
Kevin Plank statement of second law of thermodynamics
It's impossible for any device operating in a cycle to receive heat from a single reservoir and produce an amount of work,
39
Clausius statement of second law of thermodynamics
It's impossible to have a device that works in a cycle and transfers heat from a cooler body to a hotter body without work being done on the system.