Thermodynamics definitions Flashcards

1
Q

Reversible process

A

For fluid undergoing reversible process, both the fluid and the surroundings can always be returned to their original states

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2
Q

Isentropic efficiency

A

For identical start and end pressures, a ratio of reversible power to real world power. A measure of how much a steady flow process approximates to an isentropic process.

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3
Q

Adiabatic

A

No heat transfer between the fluid and its surroundings.

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4
Q

Cycle

A

A series of processes which returns a system to it initial state

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5
Q

Reservoir

A

Thermodynamic system with a heat capacity large enough that can supply or absorb a finite amount of heat and remain at constant temperature

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6
Q

Source

A

System which supplies heat

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7
Q

Sink

A

System which accepts heat

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8
Q

Isentropic

A

A process in which there is no friction and no heat transfer. Also means constant entropy

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9
Q

Entropy

A

A thermodynamic property representing the unavailability of a system’s thermal energy for conversion into mechanical work. Measures degree of disorder in the system.

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10
Q

Closed system

A

Space containing fluid with boundary between the fluid and its surroundings

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11
Q

Property

A

Numerical values which define the system. Independent of the path taken to reach its state.

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12
Q

State postulate

A

‘simple’ equilibrium whose state can be determined by 2 independent properties

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13
Q

Gauge pressure

A

Pressure referenced to atmospheric pressure

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14
Q

Absolute pressure

A

Pressure referenced to vacuum at p=0

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15
Q

2-point temp scale

A

Defined by properties of a thermometric substance. T=0 at melting point

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16
Q

Thermodynamic temp scale

A

Not dependent on properties of a substance. Absolute zero when k=0

17
Q

Zeroth law

A

Two objects at the same temperature are at thermal equilibrium

18
Q

Process

A

Transforms system from 1 equilibrium state to another

19
Q

Path

A

Transition between start and end of a process

20
Q

Equilibrium

A

Net force = 0 when multiple forces are acting on an object

21
Q

Quasi-equilibrium

A

System always remains close to equilibrium as it moves from its start to end point of process.

22
Q

Work

A

force x distance through which the force acts

23
Q

Stationary system

A

Any change in ke/pe of system is small

24
Q

Internal energy

A

Summation of all the microscopic energies in a substance. Is a property

25
Q

1st law thermodynamics

A

When any closed system is taken through a cycle, the net work done by the system upon the surroundings is equal to the net heat supplied to the system from the surroundings.

26
Q

Independent property

A

Properties which can be combined

27
Q

Extensive properties

A

Properties which depend on system size

28
Q

Specific heat capacity

A

Quantity of energy required to raise the temperature of one unit mass by one degree.

29
Q

Enthalpy

A

A combination property. It’s the sum of internal energy and a term with the sense of work, pv. H = U + PV.

30
Q

Isochoric

A

Constant volume

31
Q

Isobaric

A

Constant pressure

32
Q

Isothermal

A

No heat transfer

33
Q

Flow work

A

Work to deform part of a boundary displacing volume V at pressure P.

34
Q

Open system

A

Fluid continuously passes into and away from a system

35
Q

Steady flow rate

A

Constant mass flow rate

36
Q

Axiom

A

Something which can’t be disproved, but clearly no case exists which disproves it

37
Q

Isolated system

A

No heat, work or mass crosses the system boundary

38
Q

Kevin Plank statement of second law of thermodynamics

A

It’s impossible for any device operating in a cycle to receive heat from a single reservoir and produce an amount of work,

39
Q

Clausius statement of second law of thermodynamics

A

It’s impossible to have a device that works in a cycle and transfers heat from a cooler body to a hotter body without work being done on the system.