Thermodynamics Flashcards

1
Q

Define mechanical work

A

It is defined as the product of force and distance in the direction of the force-> the rate of work transfer measured in watts

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2
Q

Define heat

A

transitory energy exchanged due to a difference in temperature between a system and its surroundings

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3
Q

Define a system

A

a region in space containing matter under consideration within some closed surface called the boundary of the system

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4
Q

Define a boundary

A

it separates a system from the surroundings; heat and work can cross the boundary

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5
Q

Define surroundings

A

they are outside the system but close enough to be affected by changes within the system

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6
Q

Define a universe

A

a system and its surroundings form a universe

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7
Q

Define an isolated system

A

a system that cannot exchange either energy or matter outside the boundaries of the system

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8
Q

Define an open system

A

matter can cross the boundary

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9
Q

Define a closed system

A

matter cannot cross the system

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10
Q

Define a property

A

it describes the conditions of the system in a specific state

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11
Q

Define intensive properties

A

properties that are independent of the mass of the system

e.g. temperature and pressure

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12
Q

Define extensive properties

A

properties that are proportional to the mass of the system

e.g. total volume and total energy

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13
Q

Define a specific property

A

a property that is per unit mass of matter in the system

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14
Q

Define a state

A

condition of a system as defined by the relevant properties

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15
Q

Define internal energy

A

It is defined as the total energy of a closed system. It is a sum of the potential and kinetic energies of the system

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16
Q

Define equilibrium

A

a system is in thermodynamic equilibrium when no changes of state are taking place

17
Q

Define a process

A

the transition of a system from one state to another

18
Q

Define a cycle

A

a closed system passes through a series of states in such a wat that the final state is equal to the initial state

19
Q

What are the three assumptions made when using the Kinetic Theory of Gases to model the behaviour of Perfect Gasses?

A

The particles are perfectly rigid, therefore all collisions are perfectly elastic

The total volume occupied by the particles is negligible when compared to the total volume occupied by the gas

There are no attractive and repulsive forces between the particles

20
Q

Define the unified atomic mass

A

u = (Mass of C-12 atom)/12

21
Q

What is Avogadro’s Law?

A

Equal volumes of all gases contain the same number of particles when at the same temperature and pressure

22
Q

What is Dalton’s Law?

A

The pressure of a mixture of gases is equal to the sum of the partial pressures of the constituents

23
Q

Define the specific heat of a substance

A

It is defined as the quantity of heat required to cause unit temperature rise in unit mass