Thermodynamics Flashcards

1
Q

Quality

A

fraction of total mass that is vapor

x=m_g/(m_g+m_f)

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2
Q

Specific Enthalpy

A

h=u+pv

h=hf+xhfg

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3
Q

Molar Enthalpy

A

H=mh

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4
Q

Internal Energy

A

U=H-pV

u=uf+xufg

delta u = c_v*delta T

Units: kj/kg

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5
Q

Gibbs Function

A

g=h-Ts=u+pv-Ts

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6
Q

Heat Capacity (Specific Heat)

A

cv - Constant Volume

cp - Constant Pressure

Q=mc(T2-T1)

Q=heat energy

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7
Q
A
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8
Q

First law of thermodynamics

A

Q=delta U + W

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9
Q

conservation of energy for open systems

A
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10
Q

Universal Constant: R

A

8314 m^3*Pa/(kmol*k)

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11
Q

Ideal Gases undergoing Isentropic Processes

A

p_2/p_1=(v_1/v_2)^k

T_2/T_1=(v_1/v_2)^(k-1)

T_2/T_1=(p_2/p_1)^((k-1)/k)

k=c_p/c_v

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12
Q

Entropy

A

delta s = integral ds = integral dq/T

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13
Q

adiabatic process

A

A process in which no energy crosses the system boundary

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14
Q

throttling process

A

An adiabatic process in which there is no change in enthalpy, but for which there is a significant pressure drop

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15
Q

isochoric or isometric process

A

constant volume process

W=0

T/p=constant

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16
Q

polytropic process

A

A process which obeys the polytropic equation of state. (pv^n) Gases always constitute the system in polytropic processes.

pv^n=constant

W=(p2v2-p1v1)/(1-n) - closed system

W=n(p2v2-p1v1)/(1-n) - closed system

17
Q

isentropic

A

pv^k=constant

W=(p2v2-p1v1)/(1-k)

=R(T2-T1)/(1-k)

=(RT/(k-1))*(1-(p2/p1)^(k-1)/k

18
Q

isothermal

A

pv=constant

W=RTln(v2/v1)=RTln(p1/p2) - closed system

W=RTln(v2/v1)=RTln(p1/p2) - open system

19
Q

Work

A

First assume some combination of Pdv