thermodynamics Flashcards

1
Q

calorimetry

A

the measurement of heat changes

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2
Q

chemical energy

A

energy stored within the structural units of chemical substances

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3
Q

closed system

A

a system that enables exchange of energy (usually in the form of heat) but not mass with its surroundings

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4
Q

endothermic process

A

processes that absorb heat from the surroundings

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5
Q

energy

A

the capacity to do work or to produce change

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6
Q

enthalpy

A

a thermodynamic quantity used to describe heat changes taking place at a constant pressure

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7
Q

enthalpy of reaction

A

the difference between the enthalpies of the products and the enthalpies of the reactants

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8
Q

enthalpy of solution

A

the heat generated or absorbed when a certain amount of solute dissolved in a certain amount of solvent

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9
Q

exothermic process

A

processes that give off heat to the surroundings

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10
Q

first law of thermodynamics

A

energy can be converted from one form to another, but can not be created or destroyed

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11
Q

heat

A

transfer of energy between two bodies that are at different temperatures

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12
Q

heat capacity

A

the amount of heat required to raise the temperature of a given quantity of a substance by one degree celsius

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13
Q

heat of diluation

A

the heat change associated with the dilution process

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14
Q

heat of hydration

A

the change associated with the hydration process

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15
Q

heat of solution

A

the heat generated or absorbed when a certain amount of solute is dissolved in a certain amount of solvent

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16
Q

hess’s law

A

when reatants are converted to products the change in enthalpy is the same, whether the reaction takes places in one step or in series of steps

17
Q

isolated system

A

a system that does not allow the transfer of energy of either mass or energy to or from its surroundings

18
Q

lattice energy

A

the energy required to completely separate one mole of a solid ionic compound into gaseous ions

19
Q

law of conservation of energy

A

the total quantity of energy in the universe is constant

20
Q

open system

A

a system that can exchange mass and energy (usually in the form of heat) to its surroundings

21
Q

potential energy

A

energy available by virtue of an objects position

22
Q

radiant energy

A

energy transmitted in the form of waves

23
Q

specific heat

A

the amount of heat energy required to raise the temperature of one gram of a substance by one degree celsius

24
Q

standard of enthalpy of formation

A

the heat change that results when one mole of a compound is formed from its elements in their standard states

25
Q

standard of enthalpy of reaction

A

the entropy change when the reactions is carreid out under standard state conditions

26
Q

standards of state

A

the condition of 1 atm of pressure

27
Q

state function

A

a property that is determined by the state of the system

28
Q

state of a system

A

the values of all pertinent macroscopic variables of a system (pressure, temp, volume composition)

29
Q

surroundings

A

the rest of the universe outisde a system

30
Q

system

A

any specific part of the system that is of interest to us

31
Q

thermal energy

A

energy associated with the random motion of atoms and molecules

32
Q

thermochemical equation

A

an equation that shows both the mass and the enthalpy relations

33
Q

thermochemistry

A

the study of heat changes in chemical reactions

34
Q

thermodynamics

A

the scientfic study of the interconversion of heat and other forms of energy

35
Q

work

A

directed energy change resulting from a process