Thermodynamics Flashcards

1
Q

entropy, S

A

thermodynamic state function measuring disorder

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2
Q

disorder

A

randomisation of positions and motions of particles; dispersal of energy

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3
Q

Second Law of Thermodynamics

A

Spontaneous processes always increase universe entropy; at equilibrium, processes leave universe entropy unchanged

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4
Q

Third Law of Thermodynamics

A

absolute zero for entropy; the most ordered imaginable state is a perfect crystal at the lowest possible temperature 0K

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5
Q

Gibbs Energy

A

G=H-TS; maximum energy free to do useful work

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6
Q

driving force

A

generation of entropy in either (or both) the system or the surroundings which drives the reaction

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